Ion Exchange Materials: Properties and Applications fills a "two-dimensional" gap in books currently available on the subject. Firstly, there is a lack of modern comprehensive publications on the chemistry of ion exchange materials and on the relationships between their properties and practical applications. Secondly, there are few books on ion exchange chemistry that are targeted to industrial R&D specialists and research students who (i) do not work with ion exchange on a daily basis, (ii) need to develop competence in this area, and (iii) find it difficult to start studying the subject from primary scientific publications. The book bridges these gaps by describing classical and modern theoretical concepts, as well as practical approaches for using ion exchange materials. Ion exchange materials combine properties of homogeneous and heterogeneous materials. Besides being an interesting subject for investigation, they are essential in a wide variety of industrial technologies: in the chemical and biochemical industries, pharmacy, medicine, microelectronics, the nuclear industry, food production, waste treatment, and many other areas. Ion exchange is a powerful tool in chemical analysis and scientific research. The main focus in this book is on ion exchange polymers: ion exchange resins, chelating resins, imprinted (templated), and other functional polymers. It provides an in-depth study of ion exchange materials, suitable for postgraduate students and R&D industrial specialists in chemistry, chemical and biochemical technology. - Comprehensively covers the subject - Provides links between theoretical concepts, material properties, practical applications, and technical solutions - Easy to understand - requires only ground knowledge of university-level chemistry and can be read without an in-depth knowledge of mathematics - Supported with an interactive website

This book extends the frontiers of the ion exchange technologist and highlights new materials for the future.

This book presents the applications of ion-exchange materials in the area of environmental analysis and treatment. It includes chapters on applications of organic, inorganic and composite ion exchange materials and hexacyanoferrates in various fields such as chemical and biochemical separations, water purification, removal of harmful impurities, dyes and cationic and anionic complexes. This title is a highly valuable source of knowledge on ion-exchange materials and their applications suitable for postgraduate students and researchers but also to industrial R&D specialists in chemistry, chemical, and biochemical technology. Additionally, this book will provide an in-depth knowledge of ion-exchange column and operations suitable for engineers and industrialists.

This book presents the applications of ion-exchange materials in the biomedical industries. It includes topics related to the application of ion exchange chromatography in determination, extraction and separation of various compounds such as amino acids, morphine, antibiotics, nucleotides, penicillin and many more. This title is a highly valuable source of knowledge on ion-exchange materials and their applications suitable for postgraduate students and researchers but also to industrial R&D specialists in chemistry, chemical, and biochemical technology. Additionally, this book will provide an in-depth knowledge of ion-exchange column and operations suitable for engineers and industrialists.

Ion-exchange Technology I: Theory and Materials describes the theoretical principles of ion-exchange processes. More specifically, this volume focuses on the synthesis, characterization, and modelling of ion-exchange materials and their associated kinetics and equilibria. This title is a highly valuable source not only to postgraduate students and researchers but also to industrial R&D specialists in chemistry, chemical, and biochemical technology as well as to engineers and industrialists.

The book provides an in-depth discussion regarding inorganic ion exchangers for students, teachers, and researchers engaged in conducting research in chemical technology and related areas. Analytical chemists seeking simple and novel means of using easy-to-prepare chromatographic materials will find this book extremely informative. Inorganic Ion Exchangers in Chemical Analysis is unique in its discussion of column and planar chromatographic applications of amorphous synthetic inorganic ion exchangers. The book also covers the historical background of iorganic ion exchangers, their classification and present status, and the analytical aspects of these materials.

It is rare indeed that one comes in contact with a process or technique which impacts many technical disciplines. Ion exchange is such a processs. Although many books have been written on the topic of ion exchange, most have been aimed at the specialist and the graduate engineer or chemist. The author's experience in ion exchange technology has indicated that there are many specialists in the industry who do not understand ion exchange as a process. Therefore this manual has been written to aquaint and to train. The author has provided background information and hands-on experimental units that can be used to train laboratory technicians who later become assets in the industry. This material has been used by the author for in-house training and at the community college level with success. It is my sincere hope that the training obtained in this manual will, in some way, be used to improve the environment in which we live. Ion exchange technology has the potential to reduce pollution and improve water supplies when applied properly. In writing this manual I have had the benefit of valuable assistance. I am indebted to Wes MacGowan and Dr. F. X. McGarvey for helpful suggestions and continued encouragement to get the job done. I have also learned much over the years from Dr. S. Fisher, D. R. Kunin, and Dr. I. Abrams. In one way or another they too have some influence, however indirect, on this modest effort.

These Conference Proceedings deal with the papers presented at the International Conference on Ion Exchange Processes (ION-EX '90) which was held at The North East Wales Institute of Higher Education, 9- 11 July 1990. The camera-ready paper format was chosen so that delegates could receive their copy on arrival at the Conference. The Proceedings include reviews of biological materials, inorganic ion exchangers, the nuclear industry, theoretical aspects and new advances. In addition, there are research papers dealing with industrial ion exchange procedures and new materials. The Proceedings should therefore be of interest to those who need to be brought up to date in the various aspects of processes which involve ion exchange and ion chromatography which are now accepted as important in analysis, separation processes and process control. In each of these areas there have been important developments which are herein described. As Editors we should like to express our thanks to the individual authors for preparing their manuscripts in the required format and to Haydn Hughes and Linda Sneddon for their invaluable assistance in compiling these Proceedings. PETER A. WILLIAMS MICHAEL J. HUDSON V\1 CONTENTS v Preface Part 1: Biological Materials The Importance of Ion Exchange Processes in Living Systems 3 R. J. P. Williams The Use of Chemically Suppressed Ion Chromatography in Elemental Analysis 17 J. P. Senior Biological Separations Using Latex-Based Pellicular Resins 23 K.

“Ionic liquids will never find application in industry”, “I don’t understand this fad for ionic liquids” and “there is no widespread interest in these systems” are just three of quotes from the reports of referees for research proposals that I have received over the years. I wonder what these people think today. There are currently at least nine large-scale industrial uses of ionic liquids, including, we now rec- nise, the production of ?-Caprolactam (a monomer for the production of nylon-6) [1]. There has been a steady increase in the interest in ionic liquids for well over a decade and last year the number of papers and patents including ionic liquids was counted in the thousands. This remarkable achievement has been built on the hard work and enthusiasm, first of a small band of devotees, but now of huge numbers of scientists all over the world who do not see themselves as specialists in ionic liquids. The ionic liquids field continues to develop at an incredible rate. No sooner do I think that I am on top of the literature than it turns out that a whole new area of work has emerged without me noticing. Things that were once supposedly impos- 1 sible in ionic liquids, such as measuring the H NMR of solutes, are now widely applicable (see Chapter 8). Hence, collected volumes such as this are very w- come.

Instrumental Liquid Chromatography