This book presents the theory of non-equilibrium thermodynamics in a pedagogical and practical way that targets engineering applications. In it, tools to take advantage of the second as well as the first law of thermodynamics are provided.The book starts by explaining how the entropy production is the cornerstone of non-equilibrium thermodynamics — the basis to describe coupled transport phenomena, which are highly relevant for several renewable energy technologies. The book also uses entropy production as the foundation for a systematic methodology to analyze and improve energy efficiency, and shows how entropy production can be used to test the consistency of transport models. The link between transport theory and energy efficiency is also shown, and the relationship to exergy analysis is demonstrated. The theory is applied using examples from practical cases like evaporation, heat exchange, reactor optimization, distillation and more.Non-Equilibrium Thermodynamics for Engineering Applications may be used as a textbook for undergraduate and graduate university curricula containing thermodynamics or energy conversion issues at large, chemical and mechanical engineering, applied chemistry and applied physics.

The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems.The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight.

This book utilizes non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. There are large coupling effects between transport of heat, mass, charge and chemical reactions at surfaces, and it is important to know how one should properly integrate across systems where different phases are in contact. There is no other book available today that gives a prescription of how to set up flux equations for transports across heterogeneous systems.

The laws of thermodynamics have wide ranging practical applications in all branches of engineering.This invaluable textbook covers all the subject matter in a typical undergraduate course in engineering thermodynamics, and uses carefully chosen worked examples and problems to expose students to diverse applications of thermodynamics.This new edition has been revised and updated to include two new chapters on thermodynamic property relations, and the statistical interpretation of entropy. Problems with numerical answers are included at the end of each chapter. As a guide, instructors can use the examples and problems in tutorials, quizzes and examinations.

This comprehensive textbook covers engineering thermodynamics from beginner to advanced level. The presentation is concise, with material for about three full-term university courses on 700 pages, without compromising breadth or depth. First and second law of thermodynamics are developed from everyday observations with accessible and rational arguments. The laws of thermodynamics are applied to a multitude of systems and processes, from simple equilibration processes, over steam and gas power cycles, refrigerators and heat pumps, to chemical systems including fuel cells. Entropy and the second law are emphasized throughout, with focus on irreversible processes and work loss. Insightful development of theory is accompanied by detailed solutions of example problems, which teach the required technical skills while giving insight into the multitude of thermodynamic processes and applications. About 550 end-of-chapter problems highlight all important concepts and processes.

Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and lead to instabilities, fluctuations, and evolutionary systems. This book explores the unifying role of thermodynamics in natural phenomena. Nonequilibrium Thermodynamics, Second Edition analyzes the transport processes of energy, mass, and momentum transfer processes, as well as chemical reactions. It considers various processes occurring simultaneously, and provides students with more realistic analysis and modeling by accounting possible interactions between them. This second edition updates and expands on the first edition by focusing on the balance equations of mass, momentum, energy, and entropy together with the Gibbs equation for coupled processes of physical, chemical, and biological systems. Every chapter contains examples and practical problems to be solved. This book will be effective in senior and graduate education in chemical, mechanical, systems, biomedical, tissue, biological, and biological systems engineering, as well as physical, biophysical, biological, chemical, and biochemical sciences. - Will help readers in understanding and modelling some of the coupled and complex systems, such as coupled transport and chemical reaction cycles in biological systems - Presents a unified approach for interacting processes - combines analysis of transport and rate processes - Introduces the theory of nonequilibrium thermodynamics and its use in simultaneously occurring transport processes and chemical reactions of physical, chemical, and biological systems - A useful text for students taking advanced thermodynamics courses

Maximum Dissipation: Non-Equilibrium Thermodynamics and its Geometric Structure explores the thermodynamics of non-equilibrium processes in materials. The book develops a general technique created in order to construct nonlinear evolution equations describing non-equilibrium processes, while also developing a geometric context for non-equilibrium thermodynamics. Solid materials are the main focus in this volume, but the construction is shown to also apply to fluids. This volume also: • Explains the theory behind thermodynamically-consistent construction of non-linear evolution equations for non-equilibrium processes • Provides a geometric setting for non-equilibrium thermodynamics through several standard models, which are defined as maximum dissipation processes • Emphasizes applications to the time-dependent modeling of soft biological tissue Maximum Dissipation: Non-Equilibrium Thermodynamics and its Geometric Structure will be valuable for researchers, engineers and graduate students in non-equilibrium thermodynamics and the mathematical modeling of material behavior.

This book presents material for a one semester course on Transport Phenomena for senior undergraduate and graduate students in engineering and applied sciences. The study of Transport Phenomena provides the common ground and explores the connections between Thermodynamics, Fluid Mechanics, and Heat and Mass Transfer, thus giving a sound foundation for all transport equations in the broader area of Thermofluids. The chosen approach highlights the importance of Nonequilibrium Thermodynamics, particularly the second law of thermodynamics, for the development of stable transport equations -- global and local balance laws for mass, momentum, energy and entropy -- for thermofluidic systems. The study of transport processes through solutions of the equations considers mostly simple materials in simple geometries to allow for analytical solutions. This accessible approach emphasizes the general understanding of Transport Phenomena, visualizes the interplay between the different branches of Thermofluids, and thus enhances the understanding of each field, as well as their interconnections. The material covers classical subjects such as Navier-Stokes-Fourier equations, wave propagation and diffusion, shocks and flames, and includes discussions of nonequilibrium interfaces and extended thermodynamics. Irreversible losses due to entropy generation are highlighted throughout, emphasizing the link to thermodynamics and energy systems. About 140 end-of-chapter problems of varied length and difficulty teach the required technical skills while giving further insight into the multitude of Transport Phenomena.

Classic monograph treats the irreversible processes and phenomena of thermodynamics: non-equilibrium thermodynamics. Covers statistical foundations and applications of the field with special chapters on fluctuation theory, theory of stochastic processes, kinetic theory of gases, derivation of the Onsager reciprocal relations, more. 4 black-and-white illustrations.

This is the second edition of the text "Bioreaction Engineering Principles" by Jens Nielsen and John Villadsen, originally published in 1994 by Plenum Press (now part of Kluwer). Time runs fast in Biotechnology, and when Kluwer Plenum stopped reprinting the first edition and asked us to make a second, revised edition we happily accepted. A text on bioreactions written in the early 1990's will not reflect the enormous development of experimental as well as theoretical aspects of cellular reactions during the past decade. In the preface to the first edition we admitted to be newcomers in the field. One of us (JV) has had 10 more years of job training in biotechnology, and the younger author (IN) has now received international recognition for his work with the hottest topics of "modem" biotechnology. Furthermore we are happy to have induced Gunnar Liden, professor of chemical reaction engineering at our sister university in Lund, Sweden to join us as co-author of the second edition. His contribution, especially on the chemical engineering aspects of "real" bioreactors has been of the greatest value. Chapter 8 of the present edition is largely unchanged from the first edition. We wish to thank professor Martin Hjortso from LSU for his substantial help with this chapter.