The ever-increasing importance of chemical reactions at high and superhigh temperatures in crystalline, amorphous, and semicrystalline SOlids, as well as the reactions of these solids with gases, prompted the authors of this book to examine critically the literature available in this field and to present a general review of the subject. In this monograph we discuss those chemical and physicochemical points which we consider to be most important for solving a series of problems in the preparation and use of new inorganic materials. We hope that this book will be of interest to the many specialists working on inorganic materials. N. A. Toropov PREFACE Modem technology demands ever more materials with high mechanical strength, heat and chemical re sistance, fire resistance, special electrical properties, particular behavior toward active radiations, etc. The search for such materials requires the study of various chemical compounds, metallic alloys, and other fused in organic systems, especially oxide systems. Materials based on oxides begin to assume increasing importance in many fields of the new technology. In this connection the investigation of oxides and systems consisting of two and more oxides is expanding greatly.

Advances in High Temperature Chemistry, Volume 2 covers the advances in the knowledge of the high temperature behavior of materials and the complex and unfamiliar characteristics of matter at high temperature. The book discusses the dissociation energies and free energy functions of gaseous monoxides; the matrix-isolation technique applied to high temperature molecules; and the main features, the techniques for the production, detection, and diagnosis, and the applications of molecular beams in high temperatures. The text also describes the chemical research in streaming thermal plasmas, as well as the studies of the sublimation mechanism of sodium chloride, cadmium sulfide, and gallium arsenide. The temperature and emissivity measurements in the thermal imaging technique, freezing and melting point measurements of metal oxides, and phase studies on binary oxide systems at higher temperatures with a solar furnace are also encompassed. High temperature chemists and solar researchers will find the book invaluable.

This textbook introduces the reader to the elementary chemistry on which materials science depends by discussing the different classes of materials and their applications. It shows the reader how different types of materials are produced, why they possess specific properties, and how they are used in technology. Each chapter contains study questions to enable discussions and consolidation of the acquired knowledge. The new edition of this textbook is completely revised and updated to reflect the significant expansion of the field of materials chemistry over the last years, covering now also topics such as graphene, nanotubes, light emitting diodes, extreme photolithography, biomedical materials, and metal organic frameworks. From the reviews of the first edition: "This book is not only informative and comprehensive for a novice reader, but also a valuable resource for a scientist and/or an industrialist for new and novel challenges." (Materials and Manufacturing Process, June 2009) "Allcock provides a clear path by first describing basic chemical principles, then distinguishing between the various major materials groups, and finally enriching the student by offering a variety of special examples." (CHOICE, April 2009) "Proceeding logically from the basics to materials in advanced technology, it covers the fundamentals of materials chemistry, including principles of materials synthesis and materials characterization methods." (Internationale Fachzeitschrift Metall, January 2009)