Advanced Functional Solid Catalysts for Biomass Valorization presents the basic concepts in catalysis (homogeneous, heterogeneous, and enzymatic) and the properties of various kinds of heterogeneous solid catalysts, including their structure, porosity, particle size, BET surface area, acid-base, and redox properties. Useful information about biorefineries, types of biomass feedstocks, their structures and properties as well as about several potential catalytic routes for biomass upgrading to useful fuels and chemicals is provided in this book. Importantly, this book covers the most recent developments toward functionalization of various solid catalysts, optimization of catalysts' properties, developing cascade catalytic strategies, exploring reaction kinetics/mechanisms, and evaluating catalysts' stability/reusability during biomass upgrading. Current challenges and opportunities for the future biorefineries as well as for the design of advanced functional solid catalysts are critically discussed. - Describes catalysis as a promising technology for the development of eco-friendly and economically viable strategies for several important energy and environmental applications. - Covers heterogeneous solid catalysts because of their versatile benefits in terms of catalysts' synthesis, production cost, stability, and reusability as compared to homogeneous liquid catalysts. - Provides promising strategies for the design of new catalytic materials, such as carbon materials, metal–organic frameworks, zeolites, and mesoporous silicas. - Describes functional solid catalysts for developing one-pot cascade processes for efficient biomass valorization and other vital chemical transformations.

This book is part of a two-volume work that offers a unique blend of information on realistic evaluations of catalyst-based synthesis processes using green chemistry principles and the environmental sustainability applications of such processes for biomass conversion, refining, and petrochemical production. The volumes provide a comprehensive resource of state-of-the-art technologies and green chemistry methodologies from researchers, academics, and chemical and manufacturing industrial scientists. The work will be of interest to professors, researchers, and practitioners in clean energy catalysis, green chemistry, chemical engineering and manufacturing, and environmental sustainability. This volume focuses on the potentials, recent advances, and future prospects of catalysis for biomass conversion and value-added chemicals production via green catalytic routes. Readers are presented with a mechanistic framework assessing the development of product selective catalytic processes for biomass and biomass-derived feedstock conversion. The book offers a unique combination of contributions from experts working on both lab-scale and industrial catalytic processes and provides insight into the use of various catalytic materials (e.g., mineral acids, heteropolyacid, metal catalysts, zeolites, metal oxides) for clean energy production and environmental sustainability.

A comprehensive introduction to the design, synthesis, characterization, and catalytic properties of nanoporous catalysts for the biomass conversion With the specter of peak oil demand looming on the horizon, and mounting concerns over the environmental impact of greenhouse gas emissions, biomass has taken on a prominent role as a sustainable alternative fuel source. One critical aspect of the biomass challenge is the development of novel catalytic materials for effective and controllable biomass conversion. Edited by two scientists recognized internationally for their pioneering work in the field, this book focuses on nanoporous catalysts, the most promising class of catalytic materials for the conversion of biomass into fuel and other products. Although various catalysts have been used in the conversion of biomass-derived feedstocks, nanoporous catalysts exhibit high catalytic activities and/or unique product selectivities due to their large surface area, open nanopores, and highly dispersed active sites. This book covers an array of nanoporous catalysts currently in use for biomass conversion, including resins, metal oxides, carbons, mesoporous silicates, polydivinylbenzene, and zeolites. The authors summarize the design, synthesis, characterization and catalytic properties of these nanoporous catalysts for biomass conversions, discussing the features of these catalysts and considering future opportunities for developing more efficient catalysts. Topics covered include: Resins for biomass conversion Supported metal oxides/sulfides for biomass oxidation and hydrogenation Nanoporous metal oxides Ordered mesoporous silica-based catalysts Sulfonated carbon catalysts Porous polydivinylbenzene Aluminosilicate zeolites for bio-oil upgrading Rice straw Hydrogenation for sugar conversion Lignin depolymerization Timely, authoritative, and comprehensive, Nanoporous Catalysts for Biomass Conversion is a valuable working resource for academic researchers, industrial scientists and graduate students working in the fields of biomass conversion, catalysis, materials science, green and sustainable chemistry, and chemical/process engineering.

This book provides general information and data on one of the most promising renewable energy sources: biomass for its thermochemical conversion. During the last few years, there has been increasing focus on developing the processes and technologies for the conversion of biomass to liquid and gaseous fuels and chemicals, in particular to develop low-cost technologies. This book provides date-based scientific information on the most advanced and innovative processing of biomass as well as the process development elements on thermochemical processing of biomass for the production of biofuels and bio-products on (biomass-based biorefinery). The conversion of biomass to biofuels and other value-added products on the principle biorefinery offers potential from technological perspectives as alternate energy. The book covers intensive R&D and technological developments done during the last few years in the area of renewable energy utilizing biomass as feedstock and will be highly beneficial for the researchers, scientists and engineers working in the area of biomass-biofuels- biorefinery. - Provides the most advanced and innovative thermochemical conversion technology for biomass - Provides information on large scales such as thermochemical biorefinery - Useful for researchers intending to study scale up - Serves as both a textbook for graduate students and a reference book for researchers - Provides information on integration of process and technology on thermochemical conversion of biomass

New and Future Developments in Catalysis is a package of books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes. This volume covers all the biomass sources and gives detailed and in-depth coverage of all current chemical/catalytic conversion processes of biomass into liquid hydrocarbons to be further used as a feedstock for the production of not only biofuels but a large array of chemicals. - Offers an in-depth coverage of all catalytic topics of current interest and outlines the future challenges and research areas - A clear and visual description of all parameters and conditions enables the reader to draw conclusions for a particular case - Outline the catalytic processes applicable to energy generation and design of green processes

Biomass conversion into drop-in chemicals using novel heterogeneous bulk- and nano-scale catalysts is currently a hot research topic with the aim of replacing petrochemicals in the chemical industry. Considering the importance of this subject to the scientific community, Advanced Catalysis for Drop-in Chemicals provides the latest developments in the catalytic synthesis of drop-in chemicals mainly from lignocellulose, carbohydrates (cellulose, hemicellulose, C6 and C5 sugars, and their derivatives), lignin, and glycerol. The role of both heterogeneous bulk solid and nanostructured catalysts, along with their advantages and disadvantages for drop-in chemicals synthesis are critically summarized. Addressing the frontiers and prospects for using drop-in chemicals in place of petrochemicals in the chemical industry is also a key topic of this book. Describes fossil fuels, biomass, drop-in chemicals, catalysis, nano- and atomic-scale catalysts Includes pre- and post-treatment strategies for biomass upgrading Provides green catalytic processes for drop-in chemicals synthesis Outlines stabilization of nano- and atomic-scale catalysts Prospects atom-economy catalytic routes for drop-in chemicals synthesis Challenges using drop-in chemicals in place of petrochemicals in the chemical industry

This book provides state-of-the-art reviews, current research, prospects and challenges of the production of biofuels and chemicals such as furanic biofuels, biodiesel, carboxylic acids, polyols and others from lignocellulosic biomass, furfurals, syngas and γ-valerolactone with bifunctional catalysts, including catalytic, and combined biological and chemical catalysis processes. The bifunctionality of catalytic materials is a concept of not only using multifunctional solid materials as activators, but also design of materials in such a way that the catalytic materials have synergistic characteristics that promote a cascade of transformations with performance beyond that of mixed mono-functional catalysts. This book is a reference designed for researchers, academicians and industrialists in the area of catalysis, energy, chemical engineering and biomass conversion. Readers will find the wealth of information contained in chapters both useful and essential, for assessing the production and application of various biofuels and chemicals by chemical catalysis and biological techniques.

Carbon Dioxide Capture and Conversion: Advanced Materials and Process provides information about the fundamental principles and recent development of various methods and processes for CO2 mitigation and transformation. Beginning with a brief overview of recent advancements in CO2 capture and valorization technologies, the book elaborates on CO2 capture and conversion by covering nanoporous materials, biomaterials, innovative solvents, advanced membrane technology, nanocatalyst synthesis and design, cutting-edge characterization techniques as well as reaction mechanisms and kinetics. In addition to techno-economic evaluation and life-cycle assessment for CO2 capture and conversion processes, future perspectives, opportunities and current challenges regarding these processes in terms of their industrial applications, are systematically discussed. Carbon Dioxide Capture and Conversion: Advanced Materials and Process is, therefore, an essential resource for academic researchers, postgraduates, scientists, and engineers seeking fundamental knowledge and practical applications for use in their research and development, studies and industrial operations. - Includes recent developments in nanomaterials and advanced processes implemented for CO2 capture and conversion - Contains state-of-the-art CO2 capture and conversion technology written by leading experts - Offers advanced techniques of nanomaterials synthesis, characterization, evaluation, and industrial implementation in a wide range of CO2 capture and conversion processes

Sets the stage for the development of sustainable, environmentally friendly fuels, chemicals, and materials Taking millions of years to form, fossil fuels are nonrenewable resources; it is estimated that they will be depleted by the end of this century. Moreover, the production and use of fossil fuels have resulted in considerable environmental harm. The generation of environmentally friendly energy from renewable sources such as biomass is therefore essential. This book focuses on the integration of green chemistry concepts into biomass processes and conversion in order to take full advantage of the potential of biomass to replace nonsustainable resources and meet global needs for fuel as well as other chemicals and materials. The Role of Green Chemistry in Biomass Processing and Conversion features contributions from leading experts from Asia, Europe, and North America. Focusing on lignocellulosic biomass, the most abundant biomass resource, the book begins with a general introduction to biomass and biorefineries and then provides an update on the latest advances in green chemistry that support biomass processing and conversion. Next, the authors describe current and emerging biomass processing and conversion techniques that use green chemistry technologies, including: Green solvents such as ionic liquids, supercritical CO2, and water Sustainable energy sources such as microwave irradiation and sonification Green catalytic technologies Advanced membrane separation technologies The last chapter of the book explores the ecotoxicological and environmental effects of converting and using fuels, chemicals, and materials from biomass. Recommended for professionals and students in chemical engineering, green chemistry, and energy and fuels, The Role of Green Chemistry in Biomass Processing and Conversion sets a strong foundation for the development of a competitive and sustainable bioeconomy. This monograph includes a Foreword by James Clark (University of York, UK).