Understanding the energy it takes to build or break chemical bonds is essential for scientists and engineers in a wide range of innovative fields, including catalysis, nanomaterials, bioengineering, environmental chemistry, and space science. Reflecting the frequent additions and updates of bond dissociation energy (BDE) data throughout the literat

Mirroring the growth and direction of science for a century, the CRC Handbook of Chemistry and Physics, now in its 92nd edition, continues to be the most accessed and respected scientific reference in the world, used by students and Nobel Laureates. Available in its traditional print format, the Handbook is also available as an innovative interactive product on DVD and online. Among a wealth of enhancements, this edition analyzes, updates, and validates molecular formulas and weights, boiling and melting points, densities, and refractive indexes in the Physical Constants of Organic Compounds Table through comparisons with critically evaluated data from the NIST Thermodynamics Research Center. New Tables: Analytical Chemistry Abbreviations Used In Analytical Chemistry Basic Instrumental Techniques of Analytical Chemistry Correlation Table for Ultraviolet Active Functionalities Detection of Outliers in Measurements Polymer Properties Second Virial Coefficients of Polymer Solutions Updated Tables: Properties of the Elements and Inorganic Compounds Update of the Melting, Boiling, Triple, and Critical Points of the Elements Fluid Properties Major update and expansion of Viscosity of Gases table Major update and expansion of Thermal Conductivity of Gases table Major update of Properties of Cryogenic Fluids Major update of Recommended Data for Vapor-Pressure Calibration Expansion of table on the Viscosity of Liquid Metals Update of Permittivity (Dielectric Constant) of Gases table Added new refrigerant R-1234yf to Thermophysical Properties of Selected Fluids at Saturation table Molecular Structure and Spectroscopy Major update of Atomic Radii of the Elements Update of Bond Dissociation Energies Update of Characteristic Bond Lengths in Free Molecules Atomic, Molecular, and Optical Physics Update of Electron Affinities Update of Atomic and Molecular Polarizabilities Nuclear and Particle Physics Major update of the Table of the Isotopes Properties of Solids Major update and expansion of the Electron Inelastic Mean Free Paths table Update of table on Semiconducting Properties of Selected Materials Geophysics, Astronomy, and Acoustics Update of the Global Temperature Trend table to include 2010 data Health and Safety Information Major update of Threshold Limits for Airborne Contaminants The Handbook is also available as an eBook.

Mirroring the growth and direction of science for a century, the Handbook, now in its 93rd edition, continues to be the most accessed and respected scientific reference in the world. An authoritative resource consisting tables of data, its usefulness spans every discipline. This edition includes 17 new tables in the Analytical Chemistry section, a major update of the CODATA Recommended Values of the Fundamental Physical Constants and updates to many other tables. The book puts physical formulas and mathematical tables used in labs every day within easy reach. The 93rd edition is the first edition to be available as an eBook.

Celebrating the 100th anniversary of the CRC Handbook of Chemistry and Physics, this 94th edition is an update of a classic reference, mirroring the growth and direction of science for a century. The Handbook continues to be the most accessed and respected scientific reference in the science, technical, and medical communities. An authoritative resource consisting of tables of data, its usefulness spans every discipline. Originally a 116-page pocket-sized book, known as the Rubber Handbook, the CRC Handbook of Chemistry and Physics comprises 2,600 pages of critically evaluated data. An essential resource for scientists around the world, the Handbook is now available in print, eBook, and online formats. New tables: Section 7: Biochemistry Properties of Fatty Acid Methyl and Ethyl Esters Related to Biofuels Section 8: Analytical Chemistry Gas Chromatographic Retention Indices Detectors for Liquid Chromatography Organic Analytical Reagents for the Determination of Inorganic Ions Section 12: Properties of Solids Properties of Selected Materials at Cryogenic Temperatures Significantly updated and expanded tables: Section 3: Physical Constants of Organic Compounds Expansion of Diamagnetic Susceptibility of Selected Organic Compounds Section 5: Thermochemistry, Electrochemistry, and Solution Chemistry Update of Electrochemical Series Section 6: Fluid Properties Expansion of Thermophysical Properties of Selected Fluids at Saturation Major expansion and update of Viscosity of Liquid Metals Section 7: Biochemistry Update of Properties of Fatty Acids and Their Methyl Esters Section 8: Analytical Chemistry Major expansion of Abbreviations and Symbols Used in Analytical Chemistry Section 9: Molecular Structure and Spectroscopy Update of Bond Dissociation Energies Section 11: Nuclear and Particle Physics Update of Summary Tables of Particle Properties Section 14: Geophysics, Astronomy, and Acoustics Update of Atmospheric Concentration of Carbon Dioxide, 1958-2012 Update of Global Temperature Trend, 1880-2012 Major update of Speed of Sound in Various Media Section 15: Practical Laboratory Data Update of Laboratory Solvents and Other Liquid Reagents Major update of Density of Solvents as a Function of Temperature Major update of Dependence of Boiling Point on Pressure Section 16: Health and Safety Information Major update of Threshold Limits for Airborne Contaminants Appendix A: Major update of Mathematical Tables Appendix B: Update of Sources of Physical and Chemical Data

Advances in Physical Organic Chemistry, Volume 56 presents the latest reviews of recent work in physical organic chemistry. The book provides a valuable source of information that is ideal not only for physical organic chemists applying their expertise to both novel and traditional problems, but also for non-specialists across diverse areas who identify a physical organic component in their approach to research. Chapters due to be included in this release cover flavin-dependent enzyme catalysed reactions, coacervates and their properties, heavy atom tunnelling, machine learning, acidity and substituent effects. - Reviews the application of quantitative and mathematical methods to help readers understand chemical problems - Provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry - Covers organic, organometallic, bioorganic, enzymes and materials topics - Presents the only regularly published resource for reviews in physical organic chemistry - Written by authoritative experts who cover a wide range of topics that require a quantitative, molecular-level understanding of phenomena across a diverse range of disciplines

So many compounds, so many experiments reported by so many researchers using so many methods Finding reliable data on bond dissociation energies (BDEs) can be like looking for a needle in a haystack. But these data are crucial to work in chemical kinetics, free radical chemistry, organic thermochemistry, and physical organic chemistry-so where does

This multi-author contributed volume contains chapters featuring the development of the DV-Xα method and its application to a variety of problems in Materials Science and Spectroscopy written by leaders of the respective fields. The volume contains a Foreword written by the Chairs of Japanese and Korea DV-X alpha Societies. This book is aimed at individuals working in Quantum Chemistry.

Provides the background, tools, and models required to understand organic synthesis and plan chemical reactions more efficiently Knowledge of physical chemistry is essential for achieving successful chemical reactions in organic chemistry. Chemists must be competent in a range of areas to understand organic synthesis. Organic Chemistry provides the methods, models, and tools necessary to fully comprehend organic reactions. Written by two internationally recognized experts in the field, this much-needed textbook fills a gap in current literature on physical organic chemistry. Rigorous yet straightforward chapters first examine chemical equilibria, thermodynamics, reaction rates and mechanisms, and molecular orbital theory, providing readers with a strong foundation in physical organic chemistry. Subsequent chapters demonstrate various reactions involving organic, organometallic, and biochemical reactants and catalysts. Throughout the text, numerous questions and exercises, over 800 in total, help readers strengthen their comprehension of the subject and highlight key points of learning. The companion Organic Chemistry Workbook contains complete references and answers to every question in this text. A much-needed resource for students and working chemists alike, this text: -Presents models that establish if a reaction is possible, estimate how long it will take, and determine its properties -Describes reactions with broad practical value in synthesis and biology, such as C-C-coupling reactions, pericyclic reactions, and catalytic reactions -Enables readers to plan chemical reactions more efficiently -Features clear illustrations, figures, and tables -With a Foreword by Nobel Prize Laureate Robert H. Grubbs Organic Chemistry: Theory, Reactivity, and Mechanisms in Modern Synthesis is an ideal textbook for students and instructors of chemistry, and a valuable work of reference for organic chemists, physical chemists, and chemical engineers.

Organosilicon Compounds provides readers with the state-of-the-art status of organosilicon chemistry, including its theoretical, synthetic, physico-chemical and applied aspects. By including high quality content in a key strategic signing area, this work is a strong addition to chemistry offerings in organic, main group and organometallic research. Organosilicon chemistry deals with compounds containing carbon–silicon bonds, an essential part of organic and organometallic chemistry. This book presents the many milestone in the field that have been discovered during the last few years, also detailing its usage in commercial products, such as sealants, adhesives and coatings. - Features valuable contributions from prominent experts who cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects - Covers important breakthroughs in the field, along with historically significant achievements - Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) working in organometallic, organosilicon, main group element, transition metal, industrial silicon chemistry, and more

Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion, Volume 45, gives an overview of the different steps involved in the development and application of detailed kinetic mechanisms, mainly relating to pyrolysis and combustion processes. The book is divided into two parts that cover the chemistry and kinetic models and then the numerical and statistical methods. It offers a comprehensive coverage of the theory and tools needed, along with the steps necessary for practical and industrial applications. - Details thermochemical properties and "ab initio" calculations of elementary reaction rates - Details kinetic mechanisms of pyrolysis and combustion processes - Explains experimental data for improving reaction models and for kinetic mechanisms assessment - Describes surrogate fuels and molecular reconstruction of hydrocarbon liquid mixtures - Describes pollutant formation in combustion systems - Solves and validates the kinetic mechanisms using numerical and statistical methods - Outlines optimal design of industrial burners and optimization and dynamic control of pyrolysis furnaces - Outlines large eddy simulation of turbulent reacting flows