'A comprehensive review of the current state of the theoretical development in this important area of potential application of conducting polymers, and is very timely...The editor-author is to be congratulated for his marathon efforts and the production of a significant contribution to the literature.' -TRIP This three-part series provides undergraduate and graduate students in electrochemistry and materials science with a broad understanding of electroactive polymers. In Part I, renowned scientists examine the fundamental principles underlying electrochemical behavior of electroactive polymer materials. Contributors focus on the fundamentals of charge percolation and conductivity behavior associated with the membrane properties of electroactive polymer films. Part I also includes coverage of the phenomenon of heterogeneous redox catalysis at electroactive polymer modified electrodes.

This book is a systematic survey of the knowledge accumulated in this field in the last thirty years. It includes material on the thermodynamic aspects of the polymers, the theory of the mechanism of charge transport processes, and the chemical and physical properties of these compounds. Also covered are the techniques of characterization, the electrochemical methods of synthesis, and the application of these systems. Inzelt’s book is a must-read for electrochemists and others.

Electroactive polymers have been the object of increasing academic and industrial interest and in the past ten to fifteen years substantial progress has been achieved in the development and the characterization of this important new class of conducting materials. These materials are usually classified in two large groups, according to the mode of their electric transport. One group includes polymers having transport almost exclusively of the ionic type and they are often called 'polymer electrolytes' or, in a broader way, 'polymer ionics'. The other group includes polymeric materials where the transport mechanism is mainly electronic in nature and which are commonly termed 'conducting polymers'. Ionically conducting polymers or polymer ionics may be typically described as polar macromolecular solids in which one or more of a wide range of salts has been dissolved. The most classic example is the combina tion of poly(ethylene oxide), PEO, and lithium salts, LiX. These PEO-LiX polymer ionics were first described and proposed for applications just over ten years ago. The practical relevance of these new materials was im mediately recognized and in the course of a few years the field expanded tremendously with the involvement of many academic and industrial lab oratories. Following this diversified research activity, the ionic transport mechanism in polymer ionics was soon established and this has led to the development of new host polymers of various types, new salts and advanced polymer architectures which have enabled room temperature conductivity to be raised by several orders of magnitude.

This volume contains the papers presented at the UNESCO Scientific Forum on Chemistry in the Service of Mankind - Electrochemistry in Research and Development, held in Paris, June 4-6, 1984. Electrochemistry is concerned with the way electricity produces chemical changes and in turn chemical changes result in the production of electricity. This interaction forms the basis for an enormous variety of processes ranging from heavy industry through batteries to biological phenomena. Although there are many established applications, modern research has led to a great expansion in the possibilities for using electrochemistry in exciting future developments. To encourage this progress, UNESCO has set up an Expert Committee on Electrochemistry and its Applications in the European and North American region, which has already held a number of meetings devoted to specific topics. To achieve a synthesis of the main directions of development and to demonstrate the importance of these for the needs of our modern society, the Expert Committee organized a Forum on Electrochemistry in Research and Development. The object of this was to assess the future trends in research and development and to establish a dialogue between experts in electrochemistry and their colleagues in the many other disciplines which can make use of electrochemistry. The Forum was also intended to present electrochemistry and its applications in a form accessible to non-specialists so that science policy-makers will be aware of the potentialities of this subject for the future needs of mankind.

Electroactive polymers have been the object of increasing academic and industrial interest and in the past ten to fifteen years substantial progress has been achieved in the development and the characterization of this important new class of conducting materials. These materials are usually classified in two large groups, according to the mode of their electric transport. One group includes polymers having transport almost exclusively of the ionic type and they are often called 'polymer electrolytes' or, in a broader way, 'polymer ionics'. The other group includes polymeric materials where the transport mechanism is mainly electronic in nature and which are commonly termed 'conducting polymers'. Ionically conducting polymers or polymer ionics may be typically described as polar macromolecular solids in which one or more of a wide range of salts has been dissolved. The most classic example is the combina tion of poly(ethylene oxide), PEO, and lithium salts, LiX. These PEO-LiX polymer ionics were first described and proposed for applications just over ten years ago. The practical relevance of these new materials was im mediately recognized and in the course of a few years the field expanded tremendously with the involvement of many academic and industrial lab oratories. Following this diversified research activity, the ionic transport mechanism in polymer ionics was soon established and this has led to the development of new host polymers of various types, new salts and advanced polymer architectures which have enabled room temperature conductivity to be raised by several orders of magnitude.

Recognized experts present incisive analysis of both fundamental and applied problems in this continuation of a highly acclaimed series. Topics discussed include: A review of the literature on the potential-of-zero charge by Trasatti and Lust. A thorough review and discussion of nonequilibrium fluctuations in corrosion processes. A wide-ranging discussion of conducting polymers, electrochemistry, and biomimicking processes. Microwave (photo)electrochemistry, from its origins to today's research opportunities, including its relation to electrochemistry. New fluorine cell design, from model development through preliminary engineering modeling, laboratory tests, and pilot plant tests. A comprehensive account of the major and rapidly developing field of the electrochemistry of electronically conducting polymers and their applications. These authoritative studies will be invaluable for researchers in engineering, electrochemistry, analytical chemistry, materials science, physical chemistry, and corrosion science.

It is difficult to imagine how our highly evolved technological society would function, or how life would even exist on our planet, if polymers did not exist. The intensive study of polymeric systems, which has been under way for several decades, has recently yielded new insights into the properties of assemblies of these complex molecules and the physical principles that govern their behavior. These developments have included new concepts to describe aspects of the many body behavior in these systems, microscopic analyses that bring our understanding of these systems much closer to our understanding of simple liquids and solids, and the discovery of novel chemistry that these molecules can catalyze. This special topic volume of Advances in Chemical Physics surveys a number of these recent accomplishments. Supplemented with more than 250 illustrations, it provides a significant, up-to-date selection of papers by inter-nationally recognized researchers. Topics include: * Theory of Polyelectrolyte Solutions * Star Polymers: Experiment, Theory, and Simulation * Tethered Polymer Layers * Living Polymers * Transport and Kinetics in Electroactive Polymers Self-contained, authoritative, and timely, Polymeric Systems makes the cutting edge of polymer research available to scientists in every branch of chemical physics. Contributors to POLYMERIC SYSTEMS JEAN-LOUIS BARRAT, Departement de Physique des Materiaux, Universite Claude Bernard-Lyon l, France A. BAUMGARTNER, Institut fur Festkorperforschung, Germany M. A. CARIGNANO, Department of Chemistry, Purdue University, West Lafayette, Indiana LEWIS J. FETTERS, Corporate Research Science Laboratories, Exxon Research and Engineering Company, Annandale, New Jersey SANDRA C. GREER, Department of Chemical Engineering, University of Maryland at College Park GARY S. GREST, Corporate Research Science Laboratories, Exxon Research and Engineering Company, Annandale, New Jersey JOHN S. HUANG, Corporate Research Science Laboratories, Exxon Research and Engineering Company, Annandale, New Jersey JEAN-FRANCOIS JOANNY, Institut Charles Sadron, France MICHAEL E. G. LYONS, Electroactive Polymer Research Group, Physical Chemistry Laboratory, University of Dublin, Ireland M. MUTHUKUMAR, Department of Polymer Science, University of Massachusetts, Amherst, Massachusetts DIETER RICHTER, Institut fur Festkorperforschung, Germany I. SZLEIFER, Department of Chemistry, Purdue University, West Lafayette, Indiana

This second edition of the highly successful dictionary offers more than 300 new or revised terms. A distinguished panel of electrochemists provides up-to-date, broad and authoritative coverage of 3000 terms most used in electrochemistry and energy research as well as related fields, including relevant areas of physics and engineering. Each entry supplies a clear and precise explanation of the term and provides references to the most useful reviews, books and original papers to enable readers to pursue a deeper understanding if so desired. Almost 600 figures and illustrations elaborate the textual definitions. The “Electrochemical Dictionary” also contains biographical entries of people who have substantially contributed to electrochemistry. From reviews of the first edition: ‘the creators of the Electrochemical Dictionary have done a laudable job to ensure that each definition included here has been defined in precise terms in a clear and readily accessible style’ (The Electric Review) ‘It is a must for any scientific library, and a personal purchase can be strongly suggested to anybody interested in electrochemistry’ (Journal of Solid State Electrochemistry) ‘The text is readable, intelligible and very well written’ (Reference Reviews)

Electrochemistry is a well established discipline that has encompassed both applied and fundamental aspects of chemistry courses for nearly a century. In recent years, however, it has become obvious that even broader applications of this valuable technique are now available to advance knowledge and solve problems in organic, inorganic and biological chemistry. In this book, it is shown how a range of limitations that historically have restricted the use of voltammetric and related electrochemical techniques have been removed or minimised so that it is now possible to work in the gas and solid phases as well as the traditional liquid phase. Significant advances in theory, instrumentation and electrode design have also made the technique more user-friendly. The initial chapters of this book describe the basic theory and philosophy behind the modern, widespread use of voltammetric techniques. The later chapters provide examples of new areas of application and predict future possibilities for this exciting area.

Fundamentals of Electrochemistry provides the basic outline of most topics of theoretical and applied electrochemistry for students not yet familiar with this field, as well as an outline of recent and advanced developments in electrochemistry for people who are already dealing with electrochemical problems. The content of this edition is arranged so that all basic information is contained in the first part of the book, which is now rewritten and simplified in order to make it more accessible and used as a textbook for undergraduate students. More advanced topics, of interest for postgraduate levels, come in the subsequent parts. This updated second edition focuses on experimental techniques, including a comprehensive chapter on physical methods for the investigation of electrode surfaces. New chapters deal with recent trends in electrochemistry, including nano- and micro-electrochemistry, solid-state electrochemistry, and electrocatalysis. In addition, the authors take into account the worldwide renewal of interest for the problem of fuel cells and include chapters on batteries, fuel cells, and double layer capacitors.