Electrochemical Activation Of Catalysis

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I knew nothing of the work of C. G. Vayenas on NEMCA until the early nineties. Then I learned from a paper of his idea (gas interface reactions could be catalyzed electrochemically), which seemed quite marvelous; but I did not understand how it worked. Consequently, I decided to correspond with Professor Vayenas in Patras, Greece, to reach a better understanding of this concept. I think that my early papers (1946, 1947, and 1957), on the relationship between the work function of metal surfaces and electron transfer reactions thereat to particles in solution, held me in good stead to be receptive to what Vayenas told me. As the electrode potential changes, so of course, does the work function at the interface, and gas metal reactions there involve adsorbed particles which have bonding to the surface. Whether electron transfer is complete in such a case, or whether the effect is on the desorption of radicals, the work function determines the strength of their bonding, and if one varies the work function by varying the electrode potential, one can vary the reaction rate at the interface. I got the idea. After that, it has been smooth sailing. Dr. Vayenas wrote a seminal article in Modern Aspects of Electrochemistry, Number 29, and brought the field into the public eye. It has since grown and its usefulness in chemical catalytic reactions has been demonstrated and verified worldwide.

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Genre : Science
Author : Costas G. Vayenas
Publisher : Springer Science & Business Media
Release : 2007-05-08
File : 597 Pages
ISBN-13 : 9780306475511


Recent Advances In Electrochemical Promotion Of Catalysis

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This contributed volume provides a critical review of research in the field of Electrochemical Promotion of Catalysis (EPOC). It presents recent developments during the past decade that have led to a better understanding of the field and towards applications of the EPOC concept. The chapters focus on the implementation of EPOC for developing sinter-resistant catalysts, catalysts for hydrogen production, ammonia production and carbon dioxide valorization. The book also highlights the developments towards electropromoted dispersed catalysts and for self-sustained electrochemical promotion which are currently expanding. This authoritative analysis of EPOC is useful for various scientific communities working at the interface of heterogeneous catalysis, solid state electrochemistry and materials science. It is of particular interest to groups whose research focuses on developments towards a better and more sustainable future.

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Genre : Science
Author : Philippe Vernoux
Publisher : Springer Nature
Release : 2022-10-03
File : 386 Pages
ISBN-13 : 9783031138935


5th European Symposium On Electrochemical Engineering

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Materials Aspects of Electrochemical Engineering is the main theme of this symposium. It charts the way ahead for the future development and economic viability of all types of electrochemical processing.

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Genre : Technology & Engineering
Author : A. A. Wragg
Publisher : IChemE
Release : 1999
File : 358 Pages
ISBN-13 : 0852954174


Catalysis

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There is an increasing challenge for chemical industry and research institutions to find cost-efficient and environmentally sound methods of converting natural resources into fuels chemicals and energy. Catalysts are essential to these processes and the Catalysis Specialist Periodical Report series serves to highlight major developments in this area. This series provides systematic and detailed reviews of topics of interest to scientists and engineers in the catalysis field. The coverage includes all major areas of heterogeneous and homogeneous catalysis and also specific applications of catalysis such as NOx control kinetics and experimental techniques such as microcalorimetry. Each chapter is compiled by recognised experts within their specialist fields and provides a summary of the current literature. This series will be of interest to all those in academia and industry who need an up-to-date critical analysis and summary of catalysis research and applications. Catalysis will be of interest to anyone working in academia and industry that needs an up-to-date critical analysis and summary of catalysis research and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr

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Genre : Reference
Author : James J. Spivey
Publisher : Royal Society of Chemistry
Release : 1996
File : 354 Pages
ISBN-13 : 9780854042043


Handbook Of Solid State Electrochemistry

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The Handbook of Solid State Electrochemistry is a one-stop resource treating the two main areas of solid state electrochemistry: electrochemical properties of solids such as oxides, halides, and cation conductors; and electrochemical kinetics and mechanisms of reactions occurring on solid electrolytes, including gas-phase electrocatalysis. The fund

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Genre : Science
Author : P. J. Gellings
Publisher : CRC Press
Release : 2019-04-24
File : 644 Pages
ISBN-13 : 9781420049305


Encyclopedia Of Electrochemical Power Sources

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The Encyclopedia of Electrochemical Power Sources is a truly interdisciplinary reference for those working with batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. With a focus on the environmental and economic impact of electrochemical power sources, this five-volume work consolidates coverage of the field and serves as an entry point to the literature for professionals and students alike. Covers the main types of power sources, including their operating principles, systems, materials, and applications Serves as a primary source of information for electrochemists, materials scientists, energy technologists, and engineers Incorporates nearly 350 articles, with timely coverage of such topics as environmental and sustainability considerations

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Genre : Science
Author : Jürgen Garche
Publisher : Newnes
Release : 2013-05-20
File : 4532 Pages
ISBN-13 : 9780444527455


New And Future Developments In Catalysis

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New and Future Developments in Catalysis is a package of seven books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes.The various sources of environmental pollution are the theme of this volume. The volume lists all current environmentally friendly catalytic chemical processes used for environmental remediation and critically compares their economic viability. - Offers in-depth coverage of all catalytic topics of current interest and outlines future challenges and research areas - A clear and visual description of all parameters and conditions, enabling the reader to draw conclusions for a particular case - Outlines the catalytic processes applicable to energy generation and design of green processes

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Genre : Technology & Engineering
Author : Steven L Suib
Publisher : Newnes
Release : 2013-07-17
File : 631 Pages
ISBN-13 : 9780444538710


Modern Electrochemistry 2a

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This book had its nucleus in some lectures given by one of us (J. O’M. B. ) in a course on electrochemistry to students of energy conversion at the University of Pennsyl- nia. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all of whom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry which could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importance. Thus, conversion to electrochemically powered transportation systems appears to be an important step by means of which the difficulties of air pollution and the effects of an increasing concentration in the atmosphere of carbon dioxide may be met. Cor- sion is recognized as having an electrochemical basis. The synthesis of nylon now contains an important electrochemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of American organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the United States.

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Genre : Science
Author : John O'M. Bockris
Publisher : Springer Science & Business Media
Release : 2001-01-31
File : 820 Pages
ISBN-13 : 9780306461675


Emissions Control Catalysis

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The important advances achieved over the past years in all technological directions (industry, energy, and health) contributing to human well-being are unfortunately, in many cases, accompanied by a threat to the environment, with photochemical smog, stratospheric ozone depletion, acid rain, global warming, and finally climate change being the most well-known major issues. These are the results of a variety of pollutants emitted through these human activities. The indications show that we are already at a tipping point that might lead to non-linear and sudden environmental change on a global scale. Aiming to tackle these adverse effects in an attempt to mitigate any damage that has already occurred and to ensure that we are heading toward a cleaner (green) and sustainable future, scientists around the world are developing tools and techniques to understand, monitor, protect, and improve the environment. Emissions control catalysis is continuously advancing, providing novel, multifunctional, and optimally promoted using a variety of methods, nano-structured catalytic materials, and strategies (e.g., energy chemicals recycling, cyclic economy) that enable us to effectively control emissions, either of mobile or stationary sources, improving the quality of air (outdoor and indoor) and water and the energy economy. Representative cases include the abatement and/or recycling of CO2, CO, NOx, N2O, NH3, CH4, higher hydrocarbons, volatile organic compounds (VOCs), particulate matter, and specific industrial emissions (e.g., SOx, H2S, dioxins aromatics, and biogas). The “Emissions Control Catalysis” Special Issue has succeeded in collecting 22 high-quality contributions, included in this MDPI open access book, covering recent research progress in a variety of fields relevant to the above topics and/or applications, mainly on: (i) NOx catalytic reduction from cars (i.e., TWC) and industry (SCR) emissions; (ii) CO, CH4, and other hydrocarbons removal, and (iii) CO2 capture/recirculation combining emissions control with added-value chemicals production.

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Genre : Science
Author : Ioannis V. Yentekakis
Publisher : MDPI
Release : 2020-06-18
File : 448 Pages
ISBN-13 : 9783039360369


Nanotechnology In Catalysis Volumes 1 And 2

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This book is mainly based on the first and second symposia on Nanotechnology in Catalysis held in 2001 and 2002, but it also includes several contributions not presented in the symposia to round out the scope of the subject. The contents are the most up to date developments made by researchers all over the world in the catalysis field in this fascinating nanotechnology era. It reflects some of the frontier areas of nanoscience and nanotechnology in fabricating and characterizing catalysts and carrying out studies to prove their superior selectivity and activity. The field of application of nanotechnology for the development of catalysts for green chemistry is likely to grow rapidly during the next decade. This book hopes to contribute to the evolution of nanotechnology in that direction.

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Genre : Science
Author : Bing Zhou
Publisher : Springer Science & Business Media
Release : 2003-12-31
File : 416 Pages
ISBN-13 : 0306483238