Thermodynamics and Statistical Mechanics provides undergraduate chemistry students with a grounding in both classical and statistical thermodynamics. Thermodynamic quantities and relationships are introduced and developed in a coherent way, enabling students to apply thermodynamic analysis to chemical problems with confidence. Each stage in the development is well illustrated with examples. The text aims to help students understand energy, its different forms and transformations, and the key role of entropy, as applied to chemical systems, addressing questions such as: (i) How much work is performed, and how much heat transfer occurs, during chemical processes and reactions, and how do they depend on temperature? (ii) How is it possible for endothermic processes to occur spontaneously, and will a given reaction occur spontaneously? (iii) What determines the equilibrium between phases? (iv) How do temperature and pressure affect equilibrium? (v) What is the meaning of entropy? (vi) How are macroscopic thermodynamic properties related to microscopic energy levels? Ideal for the needs of undergraduate chemistry students, Tutorial Chemistry Texts is a major series consisting of short, single topic or modular texts concentrating on the fundamental areas of chemistry taught in undergraduate science courses. Each book provides a concise account of the basic principles underlying a given subject, embodying an independent-learning philosophy and including worked examples.

Thermodynamics and Statistical Mechanics Thermodynamics and Statistical Mechanics An Integrated Approach This textbook brings together the fundamentals of the macroscopic and microscopic aspects of thermal physics by presenting thermodynamics and statistical mechanics as complementary theories based on small numbers of postulates. The book is designed to give the instructor flexibility in structuring courses for advanced undergraduates and/or beginning graduate students and is written on the principle that a good text should also be a good reference. The presentation of thermodynamics follows the logic of Clausius and Kelvin while relating the concepts involved to familiar phenomena and the modern student’s knowledge of the atomic nature of matter. Another unique aspect of the book is the treatment of the mathematics involved. The essential mathematical concepts are briefly reviewed before using them, and the similarity of the mathematics to that employed in other fields of physics is emphasized. The text gives in-depth treatments of low-density gases, harmonic solids, magnetic and dielectric materials, phase transitions, and the concept of entropy. The microcanonical, canonical, and grand canonical ensembles of statistical mechanics are derived and used as the starting point for the analysis of fluctuations, blackbody radiation, the Maxwell distribution, Fermi-Dirac statistics, Bose-Einstein condensation, and the statistical basis of computer simulations.

This concise, elementary treatment illustrates the ways in which an atomic-molecular perspective yields new insights and powers operative in the realms of macroscopic thermodynamics. Starting with an analysis of some very simple microcanonical ensembles, it proceeds to the Boltzmann distribution law and a systematic exploration of the proper formulation, evaluation, and application of partition functions. The concepts of equilibrium and entropy thus acquire new significance, and readers discover how thermodynamic parameters may be calculated from spectroscopic data. Encompassing virtually all of the forms of statistical mechanics customary to undergraduate physical chemistry books, this brief text requires prior acquaintance with only the rudiments of the calculus and a few of the simplest propositions of classical thermodynamics. Appropriate for introductory college chemistry courses, it further lends itself to use as a supplementary text for independent study by more advanced students.

This 1966 account of thermodynamics was written premaritally for theoretical physicists and for experimental physicists and physical chemists wishing to enter more deeply into the fundamental principles of the subject. Although it covers elementary and advanced topics, the elementary ideas are treated from an advanced standpoint.

Thermodynamics is not the oldest of sciences. Mechanics can make that claim. Thermodynamicsisaproductofsomeofthegreatestscienti?cmindsofthe19thand 20th centuries. But it is suf?ciently established that most authors of new textbooks in thermodynamics ?nd it necessary to justify their writing of yet another textbook. I ?nd this an unnecessary exercise because of the centrality of thermodynamics as a science in physics, chemistry, biology, and medicine. I do acknowledge, however, that instruction in thermodynamics often leaves the student in a confused state. My attempt in this book is to present thermodynamics in as simple and as uni?ed a form as possible. As teachers we identify the failures of our own teachers and attempt to correct them. Although I personally acknowledge with a deep gratitude the appreciation for thermodynamics that I found as an undergraduate, I also realize that my teachers did not convey to me the sweeping grandeur of thermodynamics. Speci?cally the s- plicity and the power that James Clerk Maxwell found in the methods of Gibbs were not part of my undergraduate experience. Unfortunately some modern authors also seem to miss this central theme, choosing instead to introduce the thermodynamic potentials as only useful functions at various points in the development.

From the reviews: "This book excels by its variety of modern examples in solid state physics, magnetism, elementary particle physics [...] I can recommend it strongly as a valuable source, especially to those who are teaching basic statistical physics at our universities." Physicalia

This textbook offers an advanced undergraduate or initial graduate level introduction to topics such as kinetic theory, equilibrium statistical mechanics and the theory of fluctuations from a modern perspective. The aim is to provide the reader with the necessary tools of probability theory and thermodynamics (especially the thermodynamic potentials) to enable subsequent study at advanced graduate level. At the same time, the book offers a bird's eye view on arguments that are often disregarded in the main curriculum courses. Further features include a focus on the interdisciplinary nature of the subject and in-depth discussion of alternative interpretations of the concept of entropy. While some familiarity with basic concepts of thermodynamics and probability theory is assumed, this does not extend beyond what is commonly obtained in basic undergraduate curriculum courses.

A thorough exploration of the universal principles of thermodynamics and statistical mechanics, this volume takes an applications-oriented approach to a multitude of situations arising in physics and engineering. 1987 edition.

This proceedings provides an updated glance on recent developments in statistical physics. Contributions include thermal behavior in complex liquids, dynamical instabilities in colloidal and lattice gas models, transport and relaxation phenomena near the glass transition, as well as studies in fluctuations and kinetic theories of fluids far from equilibrium.

Lectures on Theoretical Physics, Volume V: Thermodynamics and Statistical Mechanics discusses the significant developments and problems in the study of thermodynamics and statistical mechanics. This volume contains five chapters. The first two chapters provide an overview of the various aspects and applications of thermodynamics. Chapter III contains a preliminary introduction to statistical mechanics, with an emphasis on the Brownian motion, which is the most important example of statistical fluctuations. Chapter IV describes the Boltzmann's original form of combinatorial method, in which the molecules of a gas are endowed with a physically real existence. This chapter also considers the various numerical combinations that govern the way in which the mutually indistinguishable particles are distributed over the states constituting the substance of the statistics. Chapter V explores the behavior of molecules in perfect gases following the course of historical development. This chapter covers an exact formulation of the kinetic theory of gases. Physics teachers and students will find this book invaluable.