Introductory textbook introducing the concept of competition of entropy and energy with various examples. Thermodynamics textbook explaining the roles of entropy and energy as prime movers of nature.

This book begins with primary concepts of atomic and molecular structure and of how atoms, molecules and bulk matter store and exchange energy. In the next stage, the macroscopic properties of energy and entropy, and of the constitutive properties of heat capacities are examined. From these, the concept of thermodynamic efficiency is developed. Then the notions of thermodynamic potentials and availability are introduced. With this set of concepts, the analysis of efficient energy use is presented.

This book offers an easy to read, all-embracing history of thermodynamics. It describes the long development of thermodynamics, from the misunderstood and misinterpreted to the conceptually simple and extremely useful theory that we know today. Coverage identifies not only the famous physicists who developed the field, but also engineers and scientists from other disciplines who helped in the development and spread of thermodynamics as well.

This book illustrates the basic concepts of phenomenological thermodynamics and how to move from theory to practice by considering problems in the fields of thermodynamics and energy-systems analysis. Many subjects are handled from an energetics or exergetics angle: calorimeters, evaporators, condensers, flow meters, sub or supersonic nozzles, ejectors, compressors, pumps, turbines, combustion processes, heaters, smoke stacks, cooling towers, motors, turbo-reactors, heat pumps, air conditioning, thermo-electrical generators, energy storage, and more.

Energy, Entropy, and the Flow of Nature is an attempt to present the essential principles of energetics (thermodynamics) in a manner that is straight-forward, easy to understand, and logically consistent. It arises from the difficulties author Thomas F. Sherman has seen or experienced as a student of physical chemistry, as a teacher of biochemistry and biology, and as a colleague. The central message of the book is that all natural change can be understood as a flow across a gradient, and that part of the effect of every flow is to diminish its own gradient. The book's mission is to build understanding of the central concepts, and with understanding, a degree of confidence in going forth into the many directions that the study of energy opens up. The laws of energy and entropy can indeed, in their applications, become a very complicated subject involving multivariable calculus, differential equations, and challenging problems and calculations. The fundamentals of energetics should be very straightforward, requiring relatively little mathematics--and it is the fundamentals that this book focuses on.

Nothing happens in the world without energy conversion and entropy production. These fundamental natural laws are familiar to most of us when applied to the evolution of stars, biological processes, or the working of an internal combustion engine, but what about industrial economies and wealth production, or their constant companion, pollution? Does economics conform to the First and the Second Law of Thermodynamics? In this important book, Reiner Kümmel takes us on a fascinating tour of these laws and their influence on natural, technological, and social evolution. Analyzing economic growth in Germany, Japan, and the United States in light of technological constraints on capital, labor, and energy, Professor Kümmel upends conventional economic wisdom by showing that the productive power of energy far outweighs its small share of costs, while for labor just the opposite is true. Wealth creation by energy conversion is accompanied and limited by polluting emissions that are coupled to entropy production. These facts constitute the Second Law of Economics. They take on unprecedented importance in a world that is facing peak oil, debt-driven economic turmoil, and threats from pollution and climate change. They complement the First Law of Economics: Wealth is allocated on markets, and the legal framework determines the outcome. By applying the First and Second Law we understand the true origins of wealth production, the issues that imperil the goal of sustainable development, and the technological options that are compatible both with this goal and with natural laws. The critical role of energy and entropy in the productive sectors of the economy must be realized if we are to create a road map that avoids a Dark Age of shrinking natural resources, environmental degradation, and increasing social tensions.

Computer simulation has become the main engine of development in statistical mechanics. In structural biology, computer simulation constitutes the main theoretical tool for structure determination of proteins and for calculation of the free energy of binding, which are important in drug design. Entropy and Free Energy in Structural Biology leads the reader to the simulation technology in a systematic way. The book, which is structured as a course, consists of four parts: Part I is a short course on probability theory emphasizing (1) the distinction between the notions of experimental probability, probability space, and the experimental probability on a computer, and (2) elaborating on the mathematical structure of product spaces. These concepts are essential for solving probability problems and devising simulation methods, in particular for calculating the entropy. Part II starts with a short review of classical thermodynamics from which a non-traditional derivation of statistical mechanics is devised. Theoretical aspects of statistical mechanics are reviewed extensively. Part III covers several topics in non-equilibrium thermodynamics and statistical mechanics close to equilibrium, such as Onsager relations, the two Fick's laws, and the Langevin and master equations. The Monte Carlo and molecular dynamics procedures are discussed as well. Part IV presents advanced simulation methods for polymers and protein systems, including techniques for conformational search and for calculating the potential of mean force and the chemical potential. Thermodynamic integration, methods for calculating the absolute entropy, and methodologies for calculating the absolute free energy of binding are evaluated. Enhanced by a number of solved problems and examples, this volume will be a valuable resource to advanced undergraduate and graduate students in chemistry, chemical engineering, biochemistry biophysics, pharmacology, and computational biology.

Since the landmark contributions of C. E. Shannon in 1948, and those of E. T. Jaynes about a decade later, applications of the concept of entropy and the principle of maximum entropy have proliterated in science and engineering. Recent years have witnessed a broad range of new and exciting developments in hydrology and water resources using the entropy concept. These have encompassed innovative methods for hydrologic network design, transfer of information, flow forecasting, reliability assessment for water distribution systems, parameter estimation, derivation of probability distributions, drainage-network analysis, sediment yield modeling and pollutant loading, bridge-scour analysis, construction of velocity profiles, comparative evaluation of hydrologic models, and so on. Some of these methods hold great promise for advancement of engineering practice, permitting rational alternatives to conventional approaches. On the other hand, the concepts of energy and energy dissipation are being increasingly applied to a wide spectrum of problems in environmental and water resources. Both entropy and energy dissipation have their origin in thermodynamics, and are related concepts. Yet, many of the developments using entropy seem to be based entirely on statistical interpretation and have seemingly little physical content. For example, most of the entropy-related developments and applications in water resources have been based on the information-theoretic interpretation of entropy. We believe if the power of the entropy concept is to be fully realized, then its physical basis has to be established.

This book presents the diverse and rapidly expanding field of Entropy Generation Minimization (EGM), the method of thermodynamic optimization of real devices. The underlying principles of the EGM method - also referred to as "thermodynamic optimization," "thermodynamic design," and "finite time thermodynamics" - are thoroughly discussed, and the method's applications to real devices are clearly illustrated. The EGM field has experienced tremendous growth during the 1980s and 1990s. This book places EGM's growth in perspective by reviewing both sides of the field - engineering and physics. Special emphasis is given to chronology and to the relationship between the more recent work and the pioneering work that outlined the method and the field. Entropy Generation Minimization combines the fundamental principles of thermodynamics, heat transfer, and fluid mechanics. EGM applies these principles to the modeling and optimization of real systems and processes that are characterized by finite size and finite time constraints, and are limited by heat and mass transfer and fluid flow irreversibilities. Entropy Generation Minimization provides a straightforward presentation of the principles of the EGM method, and features examples that elucidate concepts and identify recent EGM advances in engineering and physics. Modern advances include the optimization of storage by melting and solidification; heat exchanger design; power from hot-dry-rock deposits; the on & off operation of defrosting refrigerators and power plants with fouled heat exchangers; the production of ice and other solids; the maximization of power output in simple power plant models with heat transfer irreversibilities; the minimization of refrigerator power input in simple models; and the optimal collection and use of solar energy.