This book presents the derivation of the fluctuation theorems with divergent entropy production and their application to fundamental problems in statistical physics. It explores the two basic aspects of the fluctuation theorems: i) Applicability in extreme situations with divergent entropy production, concluding that the fluctuation theorems remain valid under the notion of absolute irreversibility, and ii) utility in the investigation of classical enigmas in the framework of statistical physics, i.e., Gibbs and Loschmidt paradoxes. The book offers readers an overview of the research in fundamental statistical physics. Firstly it briefly but skillfully reviews the modern development of fluctuation theorems to found the key theme of the book. Secondly it concisely discusses historical issues of statistical physics in chronological order, along with the key literature in the field. They help readers easily follow the key developments in the fundamental research of statistical physics.

This book presents the derivation of the fluctuation theorems with divergent entropy production and their application to fundamental problems in statistical physics. It explores the two basic aspects of the fluctuation theorems: i) Applicability in extreme situations with divergent entropy production, concluding that the fluctuation theorems remain valid under the notion of absolute irreversibility, and ii) utility in the investigation of classical enigmas in the framework of statistical physics, i.e., Gibbs and Loschmidt paradoxes. The book offers readers an overview of the research in fundamental statistical physics. Firstly it briefly but skillfully reviews the modern development of fluctuation theorems to found the key theme of the book. Secondly it concisely discusses historical issues of statistical physics in chronological order, along with the key literature in the field. They help readers easily follow the key developments in the fundamental research of statistical physics.

The Second Law, a cornerstone of thermodynamics, governs the average direction of dissipative, non-equilibrium processes. But it says nothing about their actual rates or the probability of fluctuations about the average. This interdisciplinary book, written and peer-reviewed by international experts, presents recent advances in the search for new non-equilibrium principles beyond the Second Law, and their applications to a wide range of systems across physics, chemistry and biology. Beyond The Second Law brings together traditionally isolated areas of non-equilibrium research and highlights potentially fruitful connections between them, with entropy production playing the unifying role. Key theoretical concepts include the Maximum Entropy Production principle, the Fluctuation Theorem, and the Maximum Entropy method of statistical inference. Applications of these principles are illustrated in such diverse fields as climatology, cosmology, crystal growth morphology, Earth system science, environmental physics, evolutionary biology and technology, fluid turbulence, microbial biogeochemistry, plasma physics, and radiative transport, using a wide variety of analytical and experimental techniques. Beyond The Second Law will appeal to students and researchers wishing to gain an understanding of entropy production and its central place in the science of non-equilibrium systems – both in detail and in terms of the bigger picture.

Entropy and entropy generation play essential roles in our understanding of many diverse phenomena ranging from cosmology to biology. Their importance is manifest in areas of immediate practical interest such as the provision of global energy as well as in others of a more fundamental flavour such as the source of order and complexity in nature. They also form the basis of most modern formulations of both equilibrium and nonequilibrium thermodynamics. Today much progress is being made in our understanding of entropy and entropy generation in both fundamental aspects and application to concrete problems. The purpose of this volume is to present some of these recent and important results in a manner that not only appeals to the entropy specialist but also makes them accessible to the nonspecialist looking for an overview of the field. This book contains fourteen contributions by leading scientists in their fields. The content covers such topics as quantum thermodynamics, nonlinear processes, gravitational and irreversible thermodynamics, the thermodynamics of Taylor dispersion, higher order transport, the mesoscopic theory of liquid crystals, simulated annealing, information and biological aspects, global energy, photovoltaics, heat and mass transport and nonlinear electrochemical systems. Audience: This work will be of value to physicists, chemists, biologists and engineers interested in the theory and applications of entropy and its generation.

The advance of scienti?c thought in ways resembles biological and geologic transformation: long periods of gradual change punctuated by episodes of radical upheaval. Twentieth century physics witnessed at least three major shifts — relativity, quantum mechanics and chaos theory — as well many lesser ones. Now, st early in the 21 , another shift appears imminent, this one involving the second law of thermodynamics. Over the last 20 years the absolute status of the second law has come under increased scrutiny, more than during any other period its 180-year history. Since the early 1980’s, roughly 50 papers representing over 20 challenges have appeared in the refereed scienti?c literature. In July 2002, the ?rst conference on its status was convened at the University of San Diego, attended by 120 researchers from 25 countries (QLSL2002) [1]. In 2003, the second edition of Le?’s and Rex’s classic anthology on Maxwell demons appeared [2], further raising interest in this emerging ?eld. In 2004, the mainstream scienti?c journal Entropy published a special edition devoted to second law challenges [3]. And, in July 2004, an echo of QLSL2002 was held in Prague, Czech Republic [4]. Modern second law challenges began in the early 1980’s with the theoretical proposals of Gordon and Denur. Starting in the mid-1990’s, several proposals for experimentally testable challenges were advanced by Sheehan, et al. By the late 1990’s and early 2000’s, a rapid succession of theoretical quantum mechanical ? challenges were being advanced by C ́ apek, et al.