Graphene-based nanocomposites are very useful in detecting toxic chemicals such as heavy metals, inorganic anions, phenolic compounds, pesticides, and chemical warfare agents. The book presents recent progress on relevant topics: Toxicity of chemicals, importance of electrochemical sensors, different types of graphene-based nanomaterials, Neurotoxins and electroanalytical detection of toxic chemicals. Keywords: Graphene-based Nanocomposites, Electrochemical Sensors, Toxic Chemicals, Sensors for Toxic Molecules, Graphene-Metal Oxides, Graphene-Metal Chalcogenides, Graphene-Polymer Nanocomposites, Graphene-Carbon Nanotubes, Graphene-Carbon Nitrides, Graphene-MOF Composites, Heavy Metals, Phenolic Compounds, Pesticides, Chemical Warfare Agents.

Metal oxide nanomaterials exhibit interesting electrical and photochemical properties because of their size, stability, and high surface area that render them as great choices in fabricating alternative electrode materials for electrochemical energy storage and sensor applications. The hybridization of metal oxides with other materials lead to the improvement in electrical conductivity, stability, and electron transfer kinetics during the electrocatalytic reactions. These key factors result in greater sensitivity of the sensor materials towards the analyte molecules. This book reviews the electrochemical determination of a variety of toxic chemical contaminants using metal oxide-based nanocomposite materials. Ultrasensitive and selective detection of toxic chemical contaminants is important and demanding, especially for monitoring and controlling environmental pollution. In recent years, metal oxide-based nanocomposite materials have shown high potential in the electrochemical detection of heavy metals, inorganic anions, phenolic compounds, pesticides, and chemical warfare reagents. Metal Oxides in Nanocomposite-Based Electrochemical Sensors for Toxic Chemicals comprehensively reviews this topic. In addition to the instrumental simplicity, the electrochemical methods show the improved sensor performance through the synergetic effect of metal oxide and other electroactive nanomaterial present in the nanocomposite. Thus, detailed information on the electrochemical sensing of toxic chemical contaminants using metal oxide-based nanomaterials are discussed. The recent progress in developing electrochemical sensors using metal oxide-based nanocomposite materials and perspectives on future opportunities in sensor research and development are addressed in the book. - Introduces the fundamentals of electrochemical sensors and fabrication of metal oxide sensors of toxic chemicals - Reviews binary, doped, metal oxide-metal, metal oxide-carbon, metal oxide-polymer, metal-boron nitride, metal oxide-clay, and metal oxide- MOF electrodes - Systematically addresses the fabrication, synthesis, performance, mechanisms, detection limits, sensitivity, advantages and limitations and future perspectives of a wide range of metal oxide-based electrochemical sensors

Graphene-Based Electrochemical Sensors for Biomolecules presents the latest on these nanomaterials that have gained a lot of attention based on their unique properties of high mechanical flexibility, large surface area, chemical stability, superior electric and thermal conductivities that render them great choices as alternative electrode materials for electrochemical energy storage and sensor applications. The hybridization of graphene with other nanomaterials induces a synergetic effect, leading to the improvement in electrical conductivity, stability and an enhancement of the electrocatalytic activity of the new nanocomposite material. This book discusses the electrochemical determination of a variety of biomolecules using graphene-based nanocomposite materials. Finally, recent progress in the development of electrochemical sensors using graphene-based nanocomposite materials and perspectives on future opportunities in sensor research and development are discussed in detail. - Covers the importance of detecting biomolecules and the application of graphene and its nanocomposite materials in the detection of a wide variety of bioanalytes - Presents easily understood fundamentals of electrochemical sensing systems and the role of graphene-based nanocomposite materials in research and development

The sixth volume in a series of handbooks on graphene research and applications The Handbook of Graphene, Volume 6: Biosensors and Advanced Sensors discusses the unique benefits that the discovery of graphene has brought to the sensing and biosensing sectors. It examines graphene's use in leading-edge technology applications and the development of a variety of graphene-based sensors. The handbook looks at how graphene can be used as an electrode, substrate, or transducer in sensor design. Graphene-based sensor detection has achieved up to femto-levels, with performances delivering the advantages of greater selectivity, sensitivity, and stability.

The book focuses on novel sensor materials and their environmental and healthcare applications, such as NO2 detection, toxic gas and biosensing, hydrazine determination, glucose sensing and the detection of toxins and pollutants on surfaces. Materials covered include catalytic nanomaterials, metal oxides, perovskites, zeolites, spinels, graphene-based gas sensors, CNT/Ni nanocomposites, glucose biosensors, single and multi-layered stacked MXenes, black phosphorus, transition metal dichalcogenides and P3OT thin films. Keywords: Toxic Gas Sensors, Biosensors, Nitrogen Dioxide Detection, Hydrazine Determination, Glucose Sensing, Catalytic Nanomaterials, Metal Oxides, Perovskites, Zeolites, Spinels, Graphene-based Gas Sensors, CNT/Ni Nanocomposites, Mxenes, Black Phosphorus, Transition Metal Dichalcogenides, P3OT Thin Films.

Graphene paper as a new form of graphene-supported nanomaterials has received worldwide attention since its first report in 2007. Due to their high flexibility, lightweight and good electrical conductivity, graphene papers have demonstrated the promising potential for crucial applications in electrochemical sensors and energy technologies among others. In this chapter, we present some examples to overview recent advances in the research and development of two-dimensional (2D) graphene papers as new materials for electrochemical sensors. The chapter covers the design, fabrication, functionalization and application evaluations of graphene papers. We first summarize the mainstream methods for fabrication of graphene papers/membranes, with the focus on chemical vapour deposition techniques and solution-processing assembly approaches. A large portion of this chapter is then devoted to the highlights of specific functionalization of graphene papers with polymer and nanoscale functional building blocks for electrochemical-sensing purposes. In terms of electrochemical-sensing applications, the emphasis is on enzyme-graphene and nanoparticle-graphene paper-based systems for the detection of glucose. We finally conclude this chapter with brief remarks and outlook.

Graphene, mother of all carbon materials, has opened up new era of exploration due to its unique properties. Graphene, one-atom thick, exhibits a unique chemical structure and outstanding electronic, optical, thermal, and mechanical properties that made it compelling for various engineering applications. Graphene and graphene-based materials are promising candidates for fabricating state-of-the-art nano-scale sensors and biosensors. They featured with good conductivity and large specific surface area thereby; graphene-based sensors/biosensors performed well with good accuracy, rapidness, high sensitivity and selectivity, low detection limits, and long-term stability. They are ideally used as gas sensors, electrochemical sensors for heavy metal ions, immunosensors and dihydronicotinamide dinucleotide NADH, DNA, catecholamine neurotransmitters, paracetamol, glucose, H2O2, hemoglobin, and myoglobin biosensors. This chapter reviews the applications of graphene in nanotechnology since it came to the field particularly in sensing and biosensing applications. It updates the reader with the scientific progress of the current use of graphene as sensors and biosensors. There is still much room for the scientific research and application development of graphene-based theory, materials, and devices. Despite the vast amount of research already conducted on graphene for various applications, the field is still growing and many questions remain to be answered.

Filling the urgent need for a professional book that specifies the applications of nanoelectrochemistry for the monitoring of persistent toxic substances, this monograph clearly describes the design concept, construction strategies and practical applications of PTS sensing interfaces based on nanoelectrochemical methods. The comprehensive and systematic information not only provides readers with the fundamentals, but also inspires them to develop PTS monitoring sensors based on functional nanostructures and nanomaterials. Of interestto chemists, electrochemistry researchers, materials researchers, environmental scientists, and companies dealing with electrochemical treatment and environment.