This book provides comprehensive analysis of a number of groundwater issues, ranging from flow to pollution problems. Several scenarios are considered throughout, including flow in leaky, unconfined, and confined geological formations, crossover flow behavior from confined to confined, to semi-confined to unconfined and groundwater pollution in dual media. Several mathematical concepts are employed to include into the mathematical models’ complexities of the geological formation, including classical differential operators, fractional derivatives and integral operators, fractal mapping, randomness, piecewise differential, and integral operators. It suggests several new and modified models to better predict anomalous behaviours of the flow and movement of pollution within complex geological formations. Numerous mathematical techniques are employed to ensure that all suggested models are well-suited, and different techniques including analytical methods and numerical methods are used to derive exact and numerical solutions of different groundwater models. Features: Includes modified numerical and analytical methods for solving new and modified models for groundwater flow and transport Presents new flow and transform models for groundwater transport in complex geological formations Examines fractal and crossover behaviors and their mathematical formulations Mathematical Analysis of Groundwater Flow Models serves as a valuable resource for graduate and PhD students as well as researchers working within the field of groundwater modeling.

This second edition is extensively revised throughout with expanded discussion of modeling fundamentals and coverage of advances in model calibration and uncertainty analysis that are revolutionizing the science of groundwater modeling. The text is intended for undergraduate and graduate level courses in applied groundwater modeling and as a comprehensive reference for environmental consultants and scientists/engineers in industry and governmental agencies. - Explains how to formulate a conceptual model of a groundwater system and translate it into a numerical model - Demonstrates how modeling concepts, including boundary conditions, are implemented in two groundwater flow codes-- MODFLOW (for finite differences) and FEFLOW (for finite elements) - Discusses particle tracking methods and codes for flowpath analysis and advective transport of contaminants - Summarizes parameter estimation and uncertainty analysis approaches using the code PEST to illustrate how concepts are implemented - Discusses modeling ethics and preparation of the modeling report - Includes Boxes that amplify and supplement topics covered in the text - Each chapter presents lists of common modeling errors and problem sets that illustrate concepts

Modeling has become an essential tool for the groundwater hydrologist. Where field data is limited, the analytic element method (AEM) is rapidly becoming the modeling method of choice, especially given the availability of affordable modeling software. Analytic Element Modeling of Groundwater Flow provides all the basics necessary to approach AEM successfully, including a presentation of fundamental concepts and a thorough introduction to Dupuit-Forchheimerflow. This book is unique in its emphasis on the actual use of analytic element models. Real-world examples complement material presented in the text. An educational version of the analytic element program GFLOW is included to allow the reader to reproduce the various solutions to groundwater flow problems discussed in the text. Researchers and graduate students in groundwater hydrology, geology, andengineering will find this book an indispensable resource. * * Provides a fundamental introduction to the use of the analytic element method. * Offers a step-by-step approach to groundwater flow modeling. * Includes an educational version of the GFLOW modeling software.

To understand hydrochemistry and to analyze natural as well as man-made impacts on aquatic systems, hydrogeochemical models have been used since the 1960’s and more frequently in recent times. Numerical groundwater flow, transport, and geochemical models are important tools besides classical deterministic and analytical approaches. Solving complex linear or non-linear systems of equations, commonly with hundreds of unknown parameters, is a routine task for a PC. Modeling hydrogeochemical processes requires a detailed and accurate water analysis, as well as thermodynamic and kinetic data as input. Thermodynamic data, such as complex formation constants and solubility-products, are often provided as databases within the respective programs. However, the description of surface-controlled reactions (sorption, cation exchange, surface complexation) and kinetically controlled reactions requires additional input data. Unlike groundwater flow and transport models, thermodynamic models, in principal, do not need any calibration. However, considering surface-controlled or kinetically controlled reaction models might be subject to calibration. Typical problems for the application of geochemical models are: • speciation • determination of saturation indices • adjustment of equilibria/disequilibria for minerals or gases • mixing of different waters • modeling the effects of temperature • stoichiometric reactions (e.g. titration) • reactions with solids, fluids, and gaseous phases (in open and closed systems) • sorption (cation exchange, surface complexation) • inverse modeling • kinetically controlled reactions • reactive transport Hydrogeochemical models depend on the quality of the chemical analysis, the boundary conditions presumed by the program, theoretical concepts (e.g.