This book aims to introduce the basic concepts involved in industrial catalytic processes. It is profusely illustrated with experimental results with the main objective of guiding how to select a suitable catalyst for specific processes. The book is divided in two parts. In the first part the basic concepts are addressed, regarding the existing theories, activity patterns and adsorption-desorption phenomena. In the second part the key experimental methods for the physicochemical characterization of catalysts are presented, as well as the currently used catalyst pre and post treatments. The last chapter describes some important in situ characterization techniques (e.g. XPS and TEM) and surface model patterns related to surface modifications occurring during the reaction. Thoroughly illustrated with microscopy images, spectroscopy data and schematics of reaction mechanisms, the book provides a powerful learning tool for students in undergraduate and graduate level courses on the field of catalysis. Exercises and resolved problems are provided, as well as experimental procedures to support laboratory classes. Furthermore, the content is presented in a carefully chosen sequence, reflecting the 30 year teaching experience of the author. The author, Professor Martin Schmal, sees the present book as a way of conveying basic knowledge needed for the development of more efficient catalysts (i.e. nanostructured materials) and novel industrial chemical processes in the fields of environmental chemistry, fine chemistry, hydrotreating of heavy oils, hydrogen production and biomass processing.

In this most up-to-date handbook each chapter contains a general introduction, followed by the principles of the immobilization and, finally, applications. In this way, it covers the most important approaches currently employed for the heterogenization of chiral catalysts, including data tables, applications, reaction types and literature citations. For chemists in both academia and industry as well as those working in the fine chemical and pharmaceutical industry.

Heterogeneous Catalysis: Materials and Applications focuses on heterogeneous catalysis applied to the elimination of atmospheric pollutants as an alternative solution for producing clean energy and the valorization of chemical products. The book helps users understand the properties of catalytic materials and catalysis phenomena governing electrocatalytic/catalytic reactions, and – more specifically – the study of surface and interface chemistry. By clustering knowledge in these fields, the book makes information available to both the academic and industrial communities. Further, it shows how heterogeneous catalysis applications can be used to solve environmental problems and convert energy through electrocatalytic reactions and chemical valorization. Sections cover nanomaterials for heterogeneous catalysis, heterogeneous catalysis mechanisms, SOX adsorption, greenhouse gases conversion, reforming reactions for hydrogen production, valorization of hydrogen energy, energy conversion and biomass valorization. - Addresses topics of increasing interest to society such as the valorization of biomass, the use of polluting gases to produce value-added products, and the optimization of catalytic materials for water splitting, fuel cells, and other devices - Discusses pollutant adsorption by industrial fume desulphurization processes - Helps improve processes for obtaining chemicals using nonconventional technologies

This textbook is a concise introduction to heterogeneous catalysis, focusing on the fundamentals and industrial implementation. It is written in a clear manner using language that is easily accessible to undergraduate students in chemical engineering and industrial chemistry. The textbook includes exercise problems and practice software. New in this edition are sections on catalyst preparation and manufacture, kinetic parameter estimation, and catalytic transport-line reactors. Solutions to all the example problems are now provided.

This book presents state-of-the-art coverage of synthesis of advanced functional materials. Unconventional synthetic routes play an important role in the synthesis of advanced materials as many new materials are metastable and cannot be synthesized by conventional methods. This book presents various synthesis methods such as conventional solid-state method, combustion method, a range of soft chemical methods, template synthesis, molecular precursor method, microwave synthesis, sono-chemical method and high-pressure synthesis. It provides a comprehensive overview of synthesis methods and covers a variety of materials, including ceramics, films, glass, carbon-based, and metallic materials. Many techniques for processing and surface functionalization are also discussed. Several engineering aspects of materials synthesis are also included. The contents of this book are useful for researchers and professionals working in the areas of materials and chemistry.

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Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers: Selective oxidations catalyzed by TS-1 and other metal-substituted zeolites Selective catalytic oxidation over ordered nanoporous metallo-aluminophosphates Selective oxidations catalyzed by mesoporous metal-silicates Liquid phase oxidation of organic compounds by supported metal-based catalysts Selective liquid phase oxidations in the presence of supported polyoxometalates Selective oxidations catalyzed by supported metal complexes Liquid phase oxidation of organic compounds by metal-organic frameworks Heterogeneous photocatalysis for selective oxidations with molecular oxygen All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications.

Magnetic nanocatalysts are garnering attention for development of greener catalytic processes due to their ease of recovery from a reaction medium. This book delves into a variety of magnetic nanocatalysts, their use in the industrial context, and recyclability. Topics covered include wastewater treatment, drug delivery, and industrial catalysis; another available volume focuses on the use of magnetic nanocatalysts in synthetic appliances and transformations.

Heterogeneous catalysis is one of the pillars of chemical and energy industries. As research on this important topic advances, heterogeneous catalysis will be a central science in driving the transition to their eventual carbon neutral operation due to the ease of separation and reusability. Readers interested in understanding the basics as well as modern trends in heterogeneous catalysis will benefit from Heterogeneous Catalysis.

This book aims to provide an overview of the design, limitations and challenges of heterogeneous catalysts for energy applications.