Tales of Suspense (1959) #66-83, Tales to Astonish (1959) #82

Collects Marvel Feature (1971) #4-10, Power Man #24-25, Black Goliath #1-5, Champions (1975) #11-13, Marvel Premiere #47-48 and material From Iron Man (1968) #44. Because you demanded it! Marvel Masterworks is proud to bring you the continuing adventures of Ant-Man — and not just one Ant-Man, either! Hank Pym’s MARVEL FEATURE series with the Wasp leads the way. Then comes Pym’s former assistant, Bill Foster, who becomes an all-new Giant-Man under the codename Black Goliath! Bill’s adventures continue into CHAMPIONS, in a story featuring the power of the Infinity Gems. Next comes the debut of Scott Lang, the man who stole the mantle of Ant-Man — literally! With work by Marvel icons including John Byrne, P. Craig Russell, Roy Thomas, Ross Andru, Herb Trimpe and more, this Masterworks is as big on talent as it is on adventure!

Collecting Iron Man (1968) #82-94 and Annual #3-4. Tony Stark is one of the Marvel Universe’s most advanced minds and experienced inventors — but those talents are about to be turned against him, shaking him to his core! Looking to exploit Stark Industries tech, the Red Ghost kidnaps Tony. In the melee, Happy Hogan dons the Iron Man armor, but suffers severe injuries — leading to a dangerous procedure that will once again turn him into the monstrous Freak! Meanwhile, NYPD Detective Michael O’Brien begins an investigation aiming to nail Tony for the death of O’Brien’s brother, the Guardsman. Add to that the Blood Brothers, the Controller, the Melter, M.O.D.O.K. and a new incarnation of the Molecule Man — Iron Man must defend himself from threats from all corners before he loses everything!

Collects X-Men (1963) #22-31. Witness the first appearance of X-Men mainstay Banshee and read the rare stories when a sixth mutant member, the Mimic, joined Professor X's squad. Also featured are the beginnings of the long-ranging Factor Three saga, and the classic battle between Mimic and the Super-Adaptoid.

When industrial villains Kearson DeWitt and the Marrs twins seize control of Tony Stark's central nervous system, he finds himself paralyzed during a battle with the Living Laser.

Collects Iron Man (1968) #95-112. It’s time for an upgrade! Iron Man increases his armor’s power as his title gains a powerful new writer: Bill Mantlo! Never before collected, Mantlo’s run delved into Tony Stark’s supporting cast, added a dose of industrial intrigue and brought back iconic adversaries. It begins with accusations of Stark Industries bribing U.S. senators, gets dangerous with the return of Ultimo and reaches a fever pitch when an all-new Guardsman comes calling! Then, in the lead-up to the blockbuster issue #100, Sunfire pits heat against iron in the prelude to the return of Tony’s greatest foe: the Mandarin! Next, the mysterious Madame Masque and the Jack of Hearts enter the fray — and the volume wraps up with an out-of-this-world battle for Wundagore Mountain!

Collects Tales of Suspense #51-65. See the return of Iron Man’s arch-nemesis, the Mandarin, and said vile villain’s origin. Then, witness the first appearance of the Avenger-to-be Hawkeye — but he’s teamed up with Black Widow against Iron Man! Plus, Iron Man must test his mettle against no less than Captain America and his own Iron Man armor.

Collects Iron Man (1968) #68-81. The world’s most famous Avenger is about to face one of his greatest challenges in the latest Iron Man Masterworks! A feud of epic proportions has been growing amongst the world’s super villains. The mysterious Black Lama pits villain against villain in a globe-spanning battle royale and the prize is ultimate power. It pits the Mandarin against the Yellow Claw, M.O.D.O.K. against the Mad Thinker and everyone against Iron Man! It’s a saga like only Marvel makes them — “The War of the Super-Villains!” The story’s surprise twists will even bring Iron Man to sunny southern California and San Diego Comic Con! (Hope he pre-registered!) Also featuring the towering threat of Ultimo and Iron Man’s return to Vietnam to rescue a friend behind enemy lines

Collects Iron Man (1968) #145-157. The hall of fame creative trio of Michelinie, Layton and Romita Jr. concludes its classic tenure with a run of stories that pushes the Armored Avenger to his limits! Tony Stark isn't the only one constantly upgrading his tech when Whiplash returns with a fearsome set of augmented powers and a new codename: Blacklash! Then Ant-Man takes his I.T. role at Stark International to super-heroic lengths! And what happens when Doctor Doom and Iron Man travel back in time to the era of King Arthur's Camelot? These two armored titans square off in "Doomquest!" Plus: The Living Laser, the Mauler and the Unicorn return to menace our man Stark. And wait until you see Iron Man's awesome new stealth armor!

Collects Spectacular Spider-Man (1976) #32-42, Annual (1979) #1; Amazing Spider-Man Annual (1964) #13; Fantastic Four (1961) #218. Peter Parker and Dr. Curt Connors (a.k.a. the Lizard) have always shared a unique bond. Both men of science, but one gifted with powers while the other was cursed. Only together can these sometimes allies, sometimes adversaries survive the unstoppable Iguana. Then, in a two-part Annual extravaganza, comes Doc Ock! All the while, Peter’s increasingly on edge. The bizarre horror of the Swarm and a battle with Morbius the Living Vampire do little to help. Then, the emergence of the Schizoid Man pushes him over the line. And on the other side is the Spider-Lizard! Can our mutated hero surivive? He’d better, or he won’t be able to team up with the FF against the Frightful Four!