This book presents the fundamentals of irreversible thermodynamics for nonlinear transport processes in gases and liquids, as well as for generalized hydrodynamics extending the classical hydrodynamics of Navier, Stokes, Fourier, and Fick. Together with its companion volume on relativistic theories, it provides a comprehensive picture of the kinetic theory formulated from the viewpoint of nonequilibrium ensembles in both nonrelativistic and, in Vol. 2, relativistic contexts. Theories of macroscopic irreversible processes must strictly conform to the thermodynamic laws at every step and in all approximations that enter their derivation from the mechanical principles. Upholding this as the inviolable tenet, the author develops theories of irreversible transport processes in fluids (gases or liquids) on the basis of irreversible kinetic equations satisfying the H theorem. They apply regardless of whether the processes are near to or far removed from equilibrium, or whether they are linear or nonlinear with respect to macroscopic fluxes or thermodynamic forces. Both irreversible Boltzmann and generalized Boltzmann equations are used for deriving theories of irreversible transport equations and generalized hydrodynamic equations, which rigorously conform to the tenet. All observables described by the so-formulated theories therefore also strictly obey the tenet.

This book presents the fundamentals of irreversible thermodynamics for nonlinear transport processes in gases and liquids, as well as for generalized hydrodynamics extending the classical hydrodynamics of Navier, Stokes, Fourier, and Fick. Together with its companion volume on nonrelativistic contexts, it provides a comprehensive picture of the relativistic covariant kinetic theory of gases and relativistic hydrodynamics of gases.Relativistic theories of macroscopic irreversible processes must strictly conform to the thermodynamic laws at every step and in all approximations that enter their derivation from the mechanical principles. Upholding this as the inviolable tenet, the author develops theories of irreversible transport processes in fluids (gases or liquids). They apply regardless of whether the processes are near to or far removed from equilibrium, or whether they are linear or nonlinear with respect to macroscopic fluxes or thermodynamic forces. The irreversible covariant Boltzmann as well as the covariant form of the Boltzmann-Nordheim-Uehling-Uhlenbeck equation is used for deriving theories of irreversible transport equations and generalized hydrodynamic equations for either classical gases or quantum gases. They all conform rigorously to the tenet. All macroscopic observables described by the so-formulated theories therefore are likewise expected to strictly obey the tenet.

This book enables the reader to learn, in a single volume, equilibrium and nonequilibrium thermodynamics as well as generalized forms of hydrodynamics for linear and nonlinear processes applied to various hydrodynamic flow processes — including chemical oscillation phenomena and pattern formations, shock wave phenomena, sound wave propagations, and Liesegang pattern formation, amongst others.Chemical Thermodynamics introduces advanced undergraduate students and graduate students to the fundamental ideas and notions of the first and second laws of thermodynamics by seamlessly combining equilibrium and nonequilibrium thermodynamics in a unicameral viewpoint based on the first and second law of thermodynamics. Part I of the book discusses equilibrium thermodynamics in historical deference, covering topics generally dealt with in traditional equilibrium thermodynamics. In Part II, the concept of entropy for reversible processes is extended and developed for thermodynamics of irreversible processes by using the concept of calortropy (heat evolution), so that the mathematical theory of macroscopic processes in matter, including a generalized form of hydrodynamics, is ensured to remain consistent with the thermodynamic laws.

Rational extended thermodynamics (RET) is the theory that is applicable to nonequilibrium phenomena out of local equilibrium. It is expressed by the hyperbolic system of field equations with local constitutive equations and is strictly related to the kinetic theory with the closure method of the hierarchies of moment equations. The book intends to present, in a systematic way, new results obtained by RET of gases in both classical and relativistic cases, and it is a natural continuation of the book "Rational Extended Thermodynamics beyond the Monatomic Gas" by the same authors published in 2015. However, this book addresses much wider topics than those of the previous book. Its contents are as follows: RET of rarefied monatomic gases and of polyatomic gases; a simplified RET theory with 6 fields being valid far from equilibrium; RET where both molecular rotational and vibrational modes exist; mixture of gases with multi-temperature. The theory is applied to several typical topics (sound waves, shock waves, etc.) and is compared with experimental data. From a mathematical point of view, RET can be regarded as a theory of hyperbolic symmetric systems, of which it is possible to conduct a qualitative analysis. The book represents a valuable resource for applied mathematicians, physicists, and engineers, offering powerful models for many potential applications such as reentering satellites into the atmosphere, semiconductors, and nanoscale phenomena.

The book describes the recent progress in some hypersonic technologies such as the aerodynamic modeling and numerical simulations of rarefied flows, boundary layer receptivity, coupled aerodynamics, and heat transfer problems, including fluid-thermal-structure interactions and launcher aerodynamic design as well as other miscellaneous topics, such as porous ceramic composite phase change control system and vehicle profile, following LQR design. Both the researchers and the students should find the material useful in their work.

In this monograph, nonequilibrium statistical mechanics is developed by means of ensemble methods on the basis of the Boltzmann equation, the generic Boltzmann equations for classical and quantum dilute gases, and a generalised Boltzmann equation for dense simple fluids. The theories are developed in forms parallel with the equilibrium Gibbs ensemble theory in a way fully consistent with the laws of thermodynamics. The generalised hydrodynamics equations are the integral part of the theory and describe the evolution of macroscopic processes in accordance with the laws of thermodynamics of systems far removed from equilibrium. Audience: This book will be of interest to researchers in the fields of statistical mechanics, condensed matter physics, gas dynamics, fluid dynamics, rheology, irreversible thermodynamics and nonequilibrium phenomena.

This is the second edition of the book “Thermodynamics of Fluids under Flow,” which was published in 2000 and has now been corrected, expanded and updated. This is a companion book to our other title Extended irreversible thermodynamics (D. Jou, J. Casas-Vázquez and G. Lebon, Springer, 4th edition 2010), and of the textbook Understanding non-equilibrium thermodynamics (G. Lebon, D. Jou and J. Casas-Vázquez, Springer, 2008. The present book is more specialized than its counterpart, as it focuses its attention on the non-equilibrium thermodynamics of flowing fluids, incorporating non-trivial thermodynamic contributions of the flow, going beyond local equilibrium theories, i.e., including the effects of internal variables and of external forcing due to the flow. Whereas the book's first edition was much more focused on polymer solutions, with brief glimpses into ideal and real gases, the present edition covers a much wider variety of systems, such as: diluted and concentrated polymer solutions, polymer blends, laminar and turbulent superfluids, phonon hydrodynamics and heat transport in nanosystems, nuclear collisions, far-from-equilibrium ideal gases, and molecular solutions. It also deals with a variety of situations, emphasizing the non-equilibrium flow contribution: temperature and entropy in flowing ideal gases, shear-induced effects on phase transitions in real gases and on polymer solutions, stress-induced migration and its application to flow chromatography, Taylor dispersion, anomalous diffusion in flowing systems, the influence of the flow on chemical reactions, and polymer degradation. The new edition is not only broader in scope, but more educational in character, and with more emphasis on applications, in keeping with our times. It provides many examples of how a deeper theoretical understanding may bring new and more efficient applications, forging links between theoretical progress and practical aims. This updated version expands on the trusted content of its predecessor, making it more interesting and useful for a larger audience.

The advance of scienti?c thought in ways resembles biological and geologic transformation: long periods of gradual change punctuated by episodes of radical upheaval. Twentieth century physics witnessed at least three major shifts — relativity, quantum mechanics and chaos theory — as well many lesser ones. Now, st early in the 21 , another shift appears imminent, this one involving the second law of thermodynamics. Over the last 20 years the absolute status of the second law has come under increased scrutiny, more than during any other period its 180-year history. Since the early 1980’s, roughly 50 papers representing over 20 challenges have appeared in the refereed scienti?c literature. In July 2002, the ?rst conference on its status was convened at the University of San Diego, attended by 120 researchers from 25 countries (QLSL2002) [1]. In 2003, the second edition of Le?’s and Rex’s classic anthology on Maxwell demons appeared [2], further raising interest in this emerging ?eld. In 2004, the mainstream scienti?c journal Entropy published a special edition devoted to second law challenges [3]. And, in July 2004, an echo of QLSL2002 was held in Prague, Czech Republic [4]. Modern second law challenges began in the early 1980’s with the theoretical proposals of Gordon and Denur. Starting in the mid-1990’s, several proposals for experimentally testable challenges were advanced by Sheehan, et al. By the late 1990’s and early 2000’s, a rapid succession of theoretical quantum mechanical ? challenges were being advanced by C ́ apek, et al.

In this monograph, the density ?uctuation theory of transport coe?cients of simple and complex liquids is described together with the kinetic theory of liquids, the generic van der Waals equation of state, and the modi?ed free volume theory. The latter two theories are integral parts of the density ?- tuation theory, which enables us to calculate the density and temperature dependence of transport coe?cients of liquids from intermolecular forces. The terms nanoscience and bioscience are the catch phrases currently in fashion in science. It seems that much of the fundamentals remaining unsolved or poorly understood in the science of condensed matter has been overshadowed by the frenzy over the more glamorous disciplines of the former, shunned by novices, and are on the verge of being forgotten. The transport coe?cients of liquids and gases and related thermophysical properties of matter appear to be one such area in the science of macroscopic properties of molecular systems and statisticalmechanicsofcondensedmatter. Evennano-andbiomaterials,h- ever, cannot be fully and appropriately understood without ?rm grounding and foundations in the macroscopic and molecular theories of transport pr- ertiesandrelatedthermophysicalpropertiesofmatterinthecondensedphase. Oneisstilldealingwithsystemsmadeupofnotafewparticlesbutamultitude of them, often too many to count, to call them few-body problems that can be understoodwithoutthehelpofstatisticalmechanicsandmacroscopicphysics. In the density ?uctuation theory of transport coe?cients, the basic approach taken is quite di?erent from the approaches taken in the conventional kinetic theories of gases and liquids.