Order In The Amorphous State Of Polymers

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In 1975, a symposium was held in Midland, Michigan, co-sponsored by the Dow Chemical Company and the then Midland Macromolecular Institute in honor of Raymond F. Boyer on the occasion of his 65th birthday and retirement from Dow. The topic of that first Boyer symposium dealt with an area of interest to Boyer, namely, polymer transitions and relaxations. One decade later, after ten years of additional fruitful scientific endeavor at MMI, Ray Boyer was again honored with a symposium, this time celebrating his 75th birthday and 10th anniversary at the Michigan Molecular Institute. The topic of the second Boyer symposium in 1985 was somewhat more focused, this time concentrating on the subject of order (or structure) in the amorphous state of polymers and the attendant polymer transitions that are observed. This volume contains the full manuscripts of the contributors to the 17th MMI International Symposium, held in Midland, Michigan on August 18-21, 1985. Eleven one-hour plenary lectures and ten 20-minute contributed papers were presented during the Symposium. An open forum panel discussion was also scheduled; the edited transcript of that session is included at the end of this volume. One of our tasks in organizing this Symposium was to attempt to gather together a number of speakers who would be able to define what, if any, physical structure might be present in anwrplwus polymers and what the nature of this order might be.

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Genre : Technology & Engineering
Author : Steven E. Keinath
Publisher : Springer Science & Business Media
Release : 2012-12-06
File : 478 Pages
ISBN-13 : 9781461318675


Structure Of The Polymer Amorphous State

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The basic problem of polymer physics is obtaining a ‘structure-propertiesa correlations for their future application for practical purposes. However, these cannot be obtained without the development of a quantitative model of the polymer structure.This problem has been actively investigated during the last 45 years.

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Genre : Science
Author : Kozlov
Publisher : CRC Press
Release : 2004-02-01
File : 478 Pages
ISBN-13 : 9789047412250


Carraher S Polymer Chemistry Ninth Edition

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Most of the advancements in communication, computers, medicine, and air and water purity are linked to macromolecules and a fundamental understanding of the principles that govern their behavior. These fundamentals are explored in Carraher's Polymer Chemistry, Ninth Edition. Continuing the tradition of previous volumes, the latest edition provides a well-rounded presentation of the principles and applications of polymers. With an emphasis on the environment and green chemistry and materials, this edition offers detailed coverage of natural and synthetic giant molecules, inorganic and organic polymers, biomacromolecules, elastomers, adhesives, coatings, fibers, plastics, blends, caulks, composites, and ceramics. Using simple fundamentals, this book demonstrates how the basic principles of one polymer group can be applied to all of the other groups. It covers reactivities, synthesis and polymerization reactions, techniques for characterization and analysis, energy absorption and thermal conductivity, physical and optical properties, and practical applications. This edition includes updated techniques, new sections on a number of copolymers, expanded emphasis on nanotechnology and nanomaterials, and increased coverage of topics including carbon nanotubes, tapes and glues, photochemistry, and more. With topics presented so students can understand polymer science even if certain parts of the text are skipped, this book is suitable as an undergraduate as well as an introductory graduate-level text. The author begins most chapters with theory followed by application, and generally addresses the most critical topics first. He provides all of the elements of an introductory text, covering synthesis, properties, applications, and characterization. This user-friendly book also contains definitions, learning objectives, questions, and additional reading in each chapter.

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Genre : Science
Author : Charles E. Carraher Jr.
Publisher : CRC Press
Release : 2016-04-19
File : 794 Pages
ISBN-13 : 9781466552203


Polymer Science And Technology

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Your search for the perfect polymers textbook ends here - with Polymer Science and Technology. By incorporating an innovative approach and consolidating in one volume the fundamentals currently covered piecemeal in several books, this efficient text simplifies the learning of polymer science. The book is divided into three main sections: po

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Genre : Science
Author : Robert O. Ebewele
Publisher : CRC Press
Release : 2000-03-23
File : 545 Pages
ISBN-13 : 9781420057805


Introduction To Polymers Third Edition

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Thoroughly updated, Introduction to Polymers, Third Edition presents the science underpinning the synthesis, characterization and properties of polymers. The material has been completely reorganized and expanded to include important new topics and provide a coherent platform for teaching and learning the fundamental aspects of contemporary polymer science. New to the Third Edition Part I This first part covers newer developments in polymer synthesis, including ‘living’ radical polymerization, catalytic chain transfer and free-radical ring-opening polymerization, along with strategies for the synthesis of conducting polymers, dendrimers, hyperbranched polymers and block copolymers. Polymerization mechanisms have been made more explicit by showing electron movements. Part II In this part, the authors have added new topics on diffusion, solution behaviour of polyelectrolytes and field-flow fractionation methods. They also greatly expand coverage of spectroscopy, including UV visible, Raman, infrared, NMR and mass spectroscopy. In addition, the Flory–Huggins theory for polymer solutions and their phase separation is treated more rigorously. Part III A completely new, major topic in this section is multicomponent polymer systems. The book also incorporates new material on macromolecular dynamics and reptation, liquid crystalline polymers and thermal analysis. Many of the diagrams and micrographs have been updated to more clearly highlight features of polymer morphology. Part IV The last part of the book contains major new sections on polymer composites, such as nanocomposites, and electrical properties of polymers. Other new topics include effects of chain entanglements, swelling of elastomers, polymer fibres, impact behaviour and ductile fracture. Coverage of rubber-toughening of brittle plastics has also been revised and expanded. While this edition adds many new concepts, the philosophy of the book remains unchanged. Largely self-contained, the text fully derives most equations and cross-references topics between chapters where appropriate. Each chapter not only includes a list of further reading to help readers expand their knowledge of the subject but also provides problem sets to test understanding, particularly of numerical aspects.

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Genre : Technology & Engineering
Author : Robert J. Young
Publisher : CRC Press
Release : 2011-06-27
File : 690 Pages
ISBN-13 : 9780849339295


Szycher S Handbook Of Polyurethanes First Edition

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Handbook of Polyurethanes serves as the first source of information of useful polymers. This new book thoroughly covers the entire spectrum of polyurethanes - from current technology to buyer's information. Discussions include: block and heteroblock systems rubber plasticity structure-property relations microphase separation catalysis of isocyanate reactions synthesis of polyurethanes for thermoplastics, thermosets, and curable compositions by either heat or U.V. energy biomedical applications of urethane elastomers castables, sealants, and caulking compounds flexible and semi-flexible foams health and safety This handbook compiles data from many sources, exhaustively illustrating the complex principles involved in polyurethane chemistry and technology. Handbook of Polyurethanes represents invaluable information for corporations, universities, or independent inventors.

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Genre : Technology & Engineering
Author : Michael Szycher, Ph.D
Publisher : CRC Press
Release : 1999-04-23
File : 698 Pages
ISBN-13 : 0849306027


Non Equilibrium Phenomena In Supercooled Fluids Glasses And Amorphous Materials Proceedings Of The Workshop

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This volume contains the Proceedings of the International Workshop on “Non-Equilibrium Phenomena in Supercooled Fluids, Glasses and Amorphous Materials”, held in Pisa in the early fall of 1995 as a joint initiative of the University of Pisa and of the Scuola Normale Superiore. The goal was to bring together liquid state physicists, chemists and engineers, to review current developments and comparatively discuss experimental facts and theoretical predictions in this vast scientific area. The core of the Workshop was a set of general lectures followed by more specific presentations on current issues in the main areas of the field. This structure has been maintained in this volume, in which a set of five overviews is followed by topically grouped contributions in the five areas of ionic glasses and glassy materials, the glass transition, viscous flow and microscopic relaxation, complex fluids, and polymers. The volume also preserves a record of the many short contributions given to the Workshop through posters, which are grouped in it under the subjects of inorganic glasses, organic glasses and complex fluids, polymers, and theoretical aspects.

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Genre :
Author : Tosi Mario P
Publisher : World Scientific
Release : 1996-09-20
File : 408 Pages
ISBN-13 : 9789814547413


Stretch Blow Molding

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Stretch Blow Molding, Third Edition, provides the latest on the blow molding process used to produce bottles of the strength required for carbonated drinks. In this updated handbook, Ottmar Brandau introduces the technology of stretch blow molding, explores practical aspects of designing and running a production line, and looks at practical issues for quality control and troubleshooting. As an experienced engineer, manager, and consultant, Brandau's focus is on optimizing the production process, improving quality, and reducing cycle time. In this new edition, the author has thoroughly reviewed the content of the book, providing updates on new developments in stretch blow molding, including neck sizes, new equipment and processes, and the economics of the process. The book is a thoroughly practical handbook which provides engineers and managers with the toolkit to improve production and engineering aspects in their own businesses, allowing them to save money, increase output, and improve competitiveness by adopting new technologies. - Provides knowledge and understanding of the latest technological and best practice developments in stretch blow molding - Includes money saving, practical strategies to optimize the production process, improve quality, and reduce cycle times - Provides a guide to the training of operators, as well as tactics on how to troubleshoot when products are faulty, productivity is low, or machinery is not operating as expected

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Genre : Technology & Engineering
Author : Ottmar Brandau
Publisher : William Andrew
Release : 2016-08-10
File : 376 Pages
ISBN-13 : 9780323462938


Electrical Properties Of Polymers

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Electrical Properties of Polymers covers topics on the electrical properties of polymers. The book discusses the electrical conduction in polymers; the structure and charge generation in low-dimensions; and the photophysical processes, energy transfer, and photoconduction in polymers. The text also describes the photovoltaic phenomena in organic solids; thermally stimulated discharge current analysis of polymers; and the polymeric electrets. The contact electrification of polymers and its elimination; and the dielectric breakdown phenomena in polymers are also considered. Materials scientists and chemists will find the book invaluable.

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Genre : Science
Author : Donald A. Seanor
Publisher : Elsevier
Release : 2013-10-22
File : 394 Pages
ISBN-13 : 9781483220123


Crystals And Crystallinity In Polymers

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Provides the tools needed to master and apply the fundamentals of polymer crystallography Using core concepts in physics, chemistry, polymer science and engineering, this book sheds new light on the complex field of polymer crystallography, enabling readers to evaluate polymer crystallization data and determine the best methods to use for their investigations. The authors set forth a variety of tested and proven methods for analyzing ordered and disordered structures in polymer crystals, including X-ray diffraction, electron diffraction, and microscopy. In addition to the basics, the book explores several advanced and emerging topics in the field such as symmetry breaking, frustration, and the principle of density-driven phase formation. Crystals and Crystallinity in Polymers introduces two new concepts in crystallinity and crystals in synthetic polymers. First, crystallinity in polymeric materials is compatible with the absence of true three-dimensional long-range order. Second, the disorder may be described as a structural feature, using the methods of X-ray scattering and electron diffraction analysis. The book begins by introducing the basic principles and methods for building structural models for the conformation of polymer crystal chains. Next, it covers: Packing of macromolecules in polymer crystals Methods for extracting structural parameters from diffraction data Defects and disorder in polymer crystals Analytical methods for diffuse scattering from disordered polymer structures Crystal habit Influence of crystal defects and structural disorder on the physical and mechanical properties of polymeric materials Crystals and Crystallinity in Polymers examines all the possible types of structural disorder generally present in polymer crystals and describes the influence of each kind of disorder on X-ray and electron diffraction patterns. Its comprehensive, expert coverage makes it possible for readers to learn and apply the fundamentals of polymer crystallography to solve a broad range of problems.

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Genre : Technology & Engineering
Author : Claudio De Rosa
Publisher : John Wiley & Sons
Release : 2013-08-26
File : 478 Pages
ISBN-13 : 9781118690796