Organic Chemistry Volume 1

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This is the first of a two-volume set designed for a course focused on the fundamentals of organic chemistry for pre-meds, and chemistry/bioscience students. It covers the major aspects of molecular structure, followed by an introduction to the techniques of physical and organic chemistry.

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Genre : Science
Author : Roger Macomber
Publisher : University Science Books
Release : 1996-04-26
File : 344 Pages
ISBN-13 : 0935702903


A Textbook Of Organic Chemistry Volume 1

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An advanced-level textbook of organic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of the four-volume series, entitled “A Textbook of Organic Chemistry – Volume I, II, III, IV”. CONTENTS: CHAPTER 1. Nature of Bonding in Organic molecules: Delocalized Chemical Bonding; Conjugation; Cross Conjugation; Resonance; Hyperconjugation; Tautomerism; Aromaticity in Benzenoid and Nonbenzenoid Compounds; Alternant and Non-Alternant Hydrocarbons; Huckel’s Rule: Energy Level of p-Molecular Orbitals; Annulenes; Antiaromaticity; Homo-Aromaticity; PMO Approach; Bonds Weaker than Covalent; Addition Compounds: Crown Ether Complexes and Cryptands, Inclusion Compounds, Cyclodextrins; Catenanes and Rotaxanes CHAPTER 2. Stereochemistry: Chirality; Elements of symmetry; Molecules with more than one chiral centre: diastereomerism; Determination of relative and absolute configuration (octant rule excluded) with special reference to lactic acid, alanine & mandelic acid; Methods of resolution; Optical purity; Prochirality; Enantiotopic and diastereotopic atoms, groups and faces; Asymmetric synthesis: cram’s rule and its modifications, prelog’s rule; Conformational analysis of cycloalkanes (upto six membered rings); Decalins; Conformations of sugars; Optical activity in absence of chiral carbon (biphenyls, allenes and spiranes); Chirality due to helical shape; Geometrical isomerism in alkenes and oximes; Methods of determining the configuration CHAPTER 3. Reaction Mechanism: Structure and Reactivity: Types of mechanisms; Types of reactions; Thermodynamic and kinetic requirements; Kinetic and thermodynamic control; Hammond’s postulate; Curtin-Hammett principle; Potential energy diagrams: Transition states and intermediates; Methods of determining mechanisms; Isotope effects; Hard and soft acids and bases; Generation, structure, stability and reactivity of carbocations, carbanions, free radicals, carbenes and nitrenes; Effect of structure on reactivity; The Hammett equation and linear free energy relationship; Substituent and reaction constants; Taft equation CHAPTER 4. Carbohydrates: Types of naturally occurring sugars; Deoxy sugars; Amino sugars; Branch chain sugars; General methods of determination of structure and ring size of sugars with particular reference to maltose, lactose, sucrose, starch and cellulose. CHAPTER 5. Natural and Synthetic Dyes: Various classes of synthetic dyes including heterocyclic dyes; Interaction between dyes and fibers; Structure elucidation of indigo and Alizarin CHAPTER 6. Aliphatic Nucleophilic Substtitution: The SN2, SN1, mixed SN1 and SN2, SNi , SN1’, SN2’, SNi’ and SET mechanisms; The neighbouring group mechanisms; neighbouring group participation by p and s bonds; anchimeric assistance; Classical and nonclassical carbocations; Phenonium ions; Common carbocation rearrangements; Applications of NMR spectroscopy in the detection of carbocations; Reactivity- effects of substrate structure, attacking nucleophile, leaving group and reaction medium; Ambident nucleophiles and regioselectivity; Phase transfer catalysis. CHAPTER 7. Aliphatic Electrophilic Substitution: Bimolecular mechanisms – SE2 and SEi; The SE1 mechanism; Electrophilic substitution accompained by double bond shifts; Effect of substrates, leaving group and the solvent polarity on the reactivity CHAPTER 8. Aromatic Electrophilic Substitution: The arenium ion: mechanism, orientation and reactivity, energy profile diagrams; The ortho/para ratio, ipso attack, orientation in other ring systems; Quantitative treatment of reactivity in substrates and electrophiles; Diazonium coupling; Vilsmeir reaction; Gattermann-Koch reaction CHAPTER 9. Aromatic Nucleophilic Substitution: The ArSN1, ArSN2, Benzyne and SRN1 mechanisms; Reactivity – effect of substrate structure, leaving group and attacking nucleophile; The von Richter, Sommelet-Hauser, and Smiles rearrangements CHAPTER 10. Elimination Reactions: The E2, E1 and E1cB mechanisms; Orientation of the double bond; Reactivity –effects of substrate structures, attacking base, the leaving group and the medium; Mechanism and orientation in pyrolytic elimination CHAPTER 11. Addition to Carbon-Carbon Multiple Bonds: Mechanistic and stereochemical aspects of addition reactions involving electrophiles, nucleophiles and free radicals; Regio–and chemoselectivity: orientation and reactivity; Addition to cyclopropane ring; Hydrogenation of double and triple bonds; Hydrogenation of aromatic rings; Hydroboration; Michael reaction; Sharpless asymmetric epoxidation. CHAPTER 12. Addition to Carbon-Hetero Multiple Bonds: Mechanism of metal hydride reduction of saturated and unsaturated carbonyl compounds, acids, esters and nitriles; Addition of Grignard reagents, organozinc and organolithium; Reagents to carbonyl and unsaturated carbonyl compounds; Wittig reaction; Mechanism of condensation reactions involving enolates – Aldol, Knoevenagel, Claisen, Mannich, Benzoin, Perkin and Stobbe reactions; Hydrolysis of esters and amides; Ammonolysis of esters.

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Genre : Science
Author : Mandeep Dalal
Publisher : Dalal Institute
Release : 2019-01-01
File : 448 Pages
ISBN-13 : 9788195242733


A Textbook Of Organic Chemistry Vol 1

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Knowledge of organic chemistry continues to move ahead in the many fronts. This Competitor's Organic Chemistry has been thoroughly covering the subject to reflect this growth. Competitor's Organic Chemistry has been divided in three volumes, I, II and III for the study of organic chemistry to the students of B. Sc. I, II and III, respectively. These books have been written according to UGC curriculum and cover full syllabus. The series of books are basically designed for the study of organic chemistry of graduate level students but these books will also be helpful and useful for many competitive examinations. The books describe the basic and fundamental concepts, basic structures, reactions and mechanisms of organic chemistry. An effort has also been made to guide the students for reaction based numerical problems of organic chemistry. The readers will observe that this text contains much and sufficient material and it goes more deeply into the subject. It is our request that readers will provide their valuable feedback about books.

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Genre : Science
Author : Dr. Akshay Kumar Shukla
Publisher : Bhartiya Sahitya Inc.
Release : 2020-06-22
File : 384 Pages
ISBN-13 : 9781613016701


Conceptual Problems In Organic Chemistry Volume I

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Genre :
Author : Singh
Publisher : Pearson Education India
Release : 2009-09
File : 248 Pages
ISBN-13 : 8131724638


Synthetic Organic Chemistry And The Nobel Prize Volume 1

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The Nobel Prize is science’s highest award, as is the case with non-science fields too, and it is therefore arguably the most internationally recognized award in the world. This unique set of volumes focuses on summarizing the Nobel Prize within organic chemistry, as well as the specializations within this specialty. Any reader researching the history of the field of organic chemistry will be interested in this work. Furthermore, it serves as an outstanding resource for providing a better understanding of the circumstances that led to these amazing discoveries and what has happened as a result, in the years since. An outstanding resource which enables readers to better understand the conditions that led to these Nobel Prize amazing discoveries To an extent the roots of organic chemistry have been forgotten or lost and this set of volumes bridges the gap Unique set of volumes, no other book publication in the field competes and only press releases announcing the prizes from recent years exist "More than any other branch of chemistry, organic chemists look to history, so the readers will certainly enjoy this compilation " Appeals to a diverse audience including upcoming as well as modern practicing chemists, and provides the historical context of these discoveries

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Genre : Science
Author : John G. D'Angelo
Publisher : CRC Press
Release : 2022-10-14
File : 109 Pages
ISBN-13 : 9781000823738


Organic Chemistry Workbook Series Volume 1 Representations Of Chemical Structures

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Confused about Lewis bond representation of organic molecules? The octet rule got you down? This workbook, written by two award-winning instructors at the University of British Columbia, has been used to help organic chemistry students for years. Using a step-by-step approach, suitable to be used in conjunction with any textbook, this workbook helps students learn critical concepts at their own pace. It is suitable for any introductory-level organic student who wants to understand the smart approach to building correct structures and understanding reactivity.

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Genre : Science
Author : Glenn Sammis
Publisher : ORCA Workbooks Publishing
Release : 2021-01-03
File : 86 Pages
ISBN-13 : 9781777203603


Stereochemistry Of Organic Compounds

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During Recent Years, Stereochemistry Has Undergone A Phenomenal Growth Both In Theory And Practice, With A Concomitant Increase Of Interest Among The Organic Chemists, Biological Chemists, Medicinal Chemists, And Pharmacologists. The Present Text Provides An Up-To-Date, Coherent; And Comprehensive Account Of The Subject Starting From The Fundamentals And Leading Up To The Latest Development As Far As Practicable. Emphasis Has Been Placed On Symmetry-Based Approach To Molecular Chirality, Stereochemical Terminologies (Modern Stereochemistry Is Replete, With Them), Topicity And Prostereoisomerism, Conformational Analysis, Dynamic Stereochemistry, Chiroptical Properties, And Assignment Of Absolute Configuration To Chiral Molecules.Dynamic Stereochemistry Has Been Discussed With Reference To Conformation-Reactivity Correlation, Stereoselective Syntheses, And Pericyclic Reactions. A Large Cross Section Of Organic Reactions With Stereochemical Implication Has Been Incorporated. Attempts Have Been Made To Familiarise The Readers With Modem Instrumental Techniques, Nuclear Magnetic Resonance In Particular, Used For Stereochemical Investigation. Each Chapter Is Provided With A Summary Which Highlights The Main Points Of The Text. Selective References, Mostly Of Textbooks, Monographs, Review Articles, And Significant Original Papers Have Been Given Extending Sometimes To Early 1991.The Book Is Expected To Fulfil The Long-Felt Need For A Comprehensive Text On Modern Organic Stereochemistry Which Is Conspicuously Absent Since The Publication Of Professor Eliels Book In 1962. The Text May Be Adopted At Any Stage Of The University Teaching And At The Same Time Be Useful To The Practising Organic Chemists.

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Genre : Science
Author : D. Nasipuri
Publisher : New Age International
Release : 1994
File : 596 Pages
ISBN-13 : 8122405703


Krishna S Advanced Organic Chemistry Volume 1

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Author :
Publisher : Krishna Prakashan Media
Release :
File : 740 Pages
ISBN-13 : 8182830788


Hand Book Of Chemistry Organic Chemistry

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Several volumes contain reports of the meetings of the Cavedish Society.

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Genre : Chemistry
Author : Leopold Gmelin
Publisher :
Release : 1871
File : 498 Pages
ISBN-13 : UCAL:B4085147


Catalogue Of The Contents Of Section A P

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Genre :
Author : Leeds Public Libraries
Publisher :
Release : 1879
File : 740 Pages
ISBN-13 : NYPL:33433089907004