A complete and timely overview of the topic, this volume of the encyclopedia imparts knowledge of fundamental principles of polymer blends. Each article is uniformly structured for easy navigation, containing the latest research & development and its basic principles and applications.

Polymer Blends, Volume 1 highlights the importance of polymer blends as a major new branch of macromolecular science. Topics range from polymer-polymer compatibility and the statistical thermodynamics of polymer blends to the phase separation behavior of polymer-polymer mixtures, transport phenomena in polymer blends, and mechanical properties of multiphase polymer blends. The optical behavior, solid state transition behavior, and rheology of polymer blends are also discussed. This book is organized into 10 chapters and begins with an overview of polymer blends, with emphasis on terminology and the effect of molecular weight on the thermodynamics of polymer blends as well as phase equilibria and transitions. The discussion then turns to the miscibility of homopolymers and copolymers, in bulk and in solution, from the experimental and theoretical viewpoints. The chapters that follow explore the statistical thermodynamics of polymer blends, paying particular attention to the Flory and lattice fluid theories, along with the phase relationship in polymer mixtures. The interfacial energy, structure, and adhesion between polymers in relation to the properties of polymer blends are considered. The final chapter examines the phenomena of low molecular weight penetrant transport. Currently accepted models for unsteady-state and steady-state permeation of polymeric materials are presented. A discussion of unsteady-state absorption and desorption behavior observed in a variety of polymer blends complements the treatment of permeation behavior. This book is intended to provide academic and industrial research scientists and technologists with a broad background in current principles and practice concerning mixed polymer systems.

A complete and timely overview of the topic, this Encyclopedia imparts knowledge of fundamental principles and their applications for academicians, scientists and researchers, while informing engineers, industrialists and entrepreneurs of the current state of the technology and its utilization. The most comprehensive source on polymer blends available on the market Offers a complete and timely overview of the topic Each article presents up to date research & development on a topic and its basic principles and applications, integrates case studies, laboratory and pilot plant experiments, and gives due reference to published and patented literature Equips academics, scientists and researchers with knowledge of fundamentals principles and their applications, and informs the engineers, industrialists and entrepreneurs about the state of the art technology and its applications

Thermodynamics is an indispensable tool for developing a large and growing fraction of new polymers and polymer blends. These two volumes show the researcher how thermodynamics can be used to rank polymer pairs in order of immiscibility, including the search for suitable chemical structure of compatibilizers. Because of the great current commercial interest in this most dynamic sector of the polymer industry, there is high interest in studying their physical and mechanical properties, their structures, and the processes of their formation and manufacture. These Books are dedicated to Analysis of the Thermodynamics of Polymer Blends. Thermodynamic behavior of blends determines the compatibility of the components, their morphological features, rheological behavior, and microphase structures. As a result, the most important physical and mechanical characteristics of blends can be identified. The information in these two volumes will be useful to all those involved in polymer research, development, analysis and advanced process engineering.

Polymer Blends, Volume 2 aims to show the importance of mixed polymer systems as a major branch of macromolecular science and provides a broad background of principles and practices in this field. Starting from where the first volume left off, the book covers topics in the area of polymer blends in Chapters 11-23. Areas of coverage include interpenetrating polymer networks; interfacial agents for polymer blends; rubber modification of plastics; fracture phenomena; coextruded multilayer polymer films and sheets; polymeric plasticizers; and polyolefin blends and their applications. The book is recommended for scientists, technologists, and engineers in the academe, research, and related industry, especially those who wish to be updated with its advances as a science.

A complete and timely overview of the topic, this volume imparts knowledge of fundamental principles and their applications for academicians, scientists and researchers, while informing engineers, industrialists and entrepreneurs of the current state of the technology and its utilization. Each article is uniformly structured for easy navigation, containing the latest research & development and its basic principles and applications, examples of case studies, laboratory and pilot plant experiments, as well as due reference to the published and patented literature.

Filling the gap for a reference dedicated to the characterization of polymer blends and their micro and nano morphologies, this book provides comprehensive, systematic coverage in a one-stop, two-volume resource for all those working in the field. Leading researchers from industry and academia, as well as from government and private research institutions around the world summarize recent technical advances in chapters devoted to their individual contributions. In so doing, they examine a wide range of modern characterization techniques, from microscopy and spectroscopy to diffraction, thermal analysis, rheology, mechanical measurements and chromatography. These methods are compared with each other to assist in determining the best solution for both fundamental and applied problems, paying attention to the characterization of nanoscale miscibility and interfaces, both in blends involving copolymers and in immiscible blends. The thermodynamics, miscibility, phase separation, morphology and interfaces in polymer blends are also discussed in light of new insights involving the nanoscopic scale. Finally, the authors detail the processing-morphology-property relationships of polymer blends, as well as the influence of processing on the generation of micro and nano morphologies, and the dependence of these morphologies on the properties of blends. Hot topics such as compatibilization through nanoparticles, miscibility of new biopolymers and nanoscale investigations of interfaces in blends are also addressed. With its application-oriented approach, handpicked selection of topics and expert contributors, this is an outstanding survey for anyone involved in the field of polymer blends for advanced technologies.

Micro- and Nanostructured Multiphase Polymer Blend Systems: Phase Morphology and Interfaces focuses on the formation of phase morphology in polymer blends and copolymers and considers various types of blends including thermosets, thermoplastics, thermoplastic vulcanizates, and structured copolymers. The book carefully debates the processing

This successor to the popular textbook, “Polymer Physics” (Springer, 1999), is the result of a quarter-century of teaching experience as well as critical comments from specialists in the various sub-fields, resulting in better explanations and more complete coverage of key topics. With a new chapter on polymer synthesis, the perspective has been broadened significantly to encompass polymer science rather than “just” polymer physics. Polysaccharides and proteins are included in essentially all chapters, while polyelectrolytes are new to the second edition. Cheap computing power has greatly expanded the role of simulation and modeling in the past two decades, which is reflected in many of the chapters. Additional problems and carefully prepared graphics aid in understanding. Two principles are key to the textbook’s appeal: 1) Students learn that, independent of the origin of the polymer, synthetic or native, the same general laws apply, and 2) students should benefit from the book without an extensive knowledge of mathematics. Taking the reader from the basics to an advanced level of understanding, the text meets the needs of a wide range of students in chemistry, physics, materials science, biotechnology, and civil engineering, and is suitable for both masters- and doctoral-level students. Praise for the previous edition: ...an excellent book, well written, authoritative, clear and concise, and copiously illustrated with appropriate line drawings, graphs and tables. - Polymer International ...an extremely useful book. It is a pleasure to recommend it to physical chemists and materials scientists, as well as physicists interested in the properties of polymeric materials. - Polymer News This valuable book is ideal for those who wish to get a brief background in polymer science as well as for those who seek a further grounding in the subject. - Colloid Polymer Science The solutions to the exercises are given in the final chapter, making it a well thought-out teaching text. - Polymer Science

Compatibilization of Polymer Blends: Micro and Nano Scale Phase Morphologies, Interphase Characterization and Properties offers a comprehensive approach to the use of compatibilizers in polymer blends, examining both fundamental and advanced knowledge in the field. The book begins by introducing polymer blends, describing thermodynamics, miscibility, and phase separation, and explaining the main concepts of compatibilization. Other sections cover theoretical approaches for nearly compatible blends, incompatible blends, nanofillers, physical compatibilization, reactive compatibilization, morphological and structural characterization, and physico-mechanical characterization. Finally, key application areas are covered, including biomedical applications, packaging and automobile engineering. While this book will be a highly valuable reference source for academics, researchers and postgraduate students interested in polymer blends, it will also be ideal for anyone involved in the fields of polymer science, polymer chemistry, polymer physics, materials science, scientists, R&D professionals, and engineers in involved in the development or engineering of polymer products. - Offers detailed and systematic coverage of essential and advanced topics relating to the compatibilization of polymer blends - Presents a critical analysis of the effect of compatibilization on morphology and thermal, mechanical, electrical and viscoelastic properties of polymer blends - Draws on novel studies and state-of-the-art research, discussing the latest issues and developments