Since their discovery single-walled carbon nanotubes (SWNTs) have gained the interest of many scientists and engineers due to their prominent structural, mechanical and electronic properties which make them applicable in various areas including electronics, chemical and biological sensing and reinforced composite materials. Although SWNTs have many application areas their use can be limited since they are synthesised as a mixture of metallic and semiconducting species with different diameters and helicities and they have limited solubility in aqueous and non-aqueous solvents. Covalent modification of SWNTs is an important tool to introduce new functional groups onto the surface of nanotubes to improve their solubility and processability. It can also be used to separate metallic from semiconducting nanotubes. The work presented here has concentrated on the non-disruptive covalent modification of SWNTs using pyridine diazonium salt addition, 1,3-dipolar cycloaddition and reductive alkylation. The selectivitiy of the addition was probed by UV-vis-NIR and Raman spectroscopy where the metallic were found to be more selective than semiconducting SWNTs. The location and distribution of the functional groups was determined by AFM using electrostatic interactions with gold nanoparticles. Rheological data showed that the pyridine modified SWNTs were able to act as crosslinkers and hydrogen bond to poly(acrylic acid) to form SWNT hydrogels. The indolizine modified SWNTs, emitted blue light when excited ca. 330 nm, were capable of sensing 4-nitrophenol, 3-nitrophenol, 2-nitrophenol, 2-nitrosotoluene and 2,4-dinitrotoluene with a detection limit of ca. 10-8 M. The modified SWNTs were further characterised using FTIR, XPS, TGA-MS and optical microscopy.

Discover the go-to handbook for developers and application-oriented researchers who use carbon nanotubes in real products Carbon nanotubes have held much interest for researchers since their discovery in 1991. Due to their low mass density, large aspect ratio, and unique physical, chemical, and electronic properties, they provide a fertile ground for innovation in nanoscale applications. The development of chemical modifications that can enhance the poor dispersion of carbon nanotubes in solvents and improve interactions with other materials have enabled extensive industrial applications in a variety of fields. As the chemistry of carbon nanotubes and their functionalization becomes better understood, Chemically Modified Carbon Nanotubes for Commercial Applications presents the most recent developments of chemically modified carbon nanotubes and emphasizes the broad appeal for commercial purposes along many avenues of interest. The book reviews their already realized and prospective applications in fields such as electronics, photonics, separation science, food packaging, environmental monitoring and protecting, sensing technology, and biomedicine. By focusing on their commercialization prospects, this resource offers a unique approach to a significant and cutting-edge discipline. Chemically Modified Carbon Nanotubes for Commercial Applications readers will also find: Case studies that emphasize the information presented in each chapter Each chapter includes important websites and suggested reading materials Discussion of current applications of the relevant methodologies in every chapter A look at future perspectives in each application area to highlight the scope for next steps within the industry Chemically Modified Carbon Nanotubes for Commercial Applications is a valuable reference for material scientists, chemists (especially those focused on environmental concerns), and chemical and materials engineering scientists working in R&D and academia who want to learn more about chemically modified carbon nanotubes for various scalable commercial applications. It is also a useful resource for a broad audience: anyone interested in the fields of nanomaterials, nanoadsorbents, nanomedicine, bioinspired nanomaterials, nanotechnology, nanodevices, nanocomposites, biomedical application of nanomaterials, nano-engineering, and high energy applications.

Carbon nanotubes represent one of the most exciting research areas in modern science. These molecular-scale carbon tubes are the stiffest and strongest fibres known, with remarkable electronic properties, and potential applications in a wide range of fields. Carbon Nanotube Science is a concise, accessible book, presenting the basic knowledge that graduates and researchers need to know. Based on the successful Carbon Nanotubes and Related Structures, this book focuses solely on carbon nanotubes, covering the major advances made in recent years in this rapidly developing field. Chapters focus on electronic properties, chemical and bimolecular functionalisation, nanotube composites and nanotube-based probes and sensors. The book begins with a comprehensive discussion of synthesis, purification and processing methods. With its comprehensive coverage of this active research field, this book will appeal to researchers in a broad range of disciplines, including nanotechnology, engineering, materials science and physics.

Since their discovery more than a decade ago, carbon nanotubes (CNTs) have held scientists and engineers in captive fascination, seated on the verge of enormous breakthroughs in areas such as medicine, electronics, and materials science, to name but a few. Taking a broad look at CNTs and the tools used to study them, Carbon Nanotubes: Properties and Applications comprises the efforts of leading nanotube researchers led by Michael O’Connell, protégé of the late father of nanotechnology, Richard Smalley. Each chapter is a self-contained treatise on various aspects of CNT synthesis, characterization, modification, and applications. The book opens with a general introduction to the basic characteristics and the history of CNTs, followed by discussions on synthesis methods and the growth of “peapod” structures. Coverage then moves to electronic properties and band structures of single-wall nanotubes (SWNTs), magnetic properties, Raman spectroscopy of electronic and chemical behavior, and electromechanical properties and applications in NEMS (nanoelectromechanical systems). Turning to applications, the final sections of the book explore mechanical properties of SWNTs spun into fibers, sidewall functionalization in composites, and using SWNTs as tips for scanning probe microscopes. Taking a fresh look at this burgeoning field, Carbon Nanotubes: Properties and Applications points the way toward making CNTs commercially viable.

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Carbon nanotubes are rolled up graphene sheets with a quasi-one-dimensional structure of nanometer-scale diameter. In these last twenty years, carbon nanotubes have attracted much attention from physicists, chemists, material scientists, and electronic device engineers, because of their excellent structural, electronic, optical, chemical and mechanical properties. More recently, demand for innovative industrial applications of carbon nanotubes is increasing. This book covers recent research topics regarding syntheses techniques of carbon nanotubes and nanotube-based composites, and their applications. The chapters in this book will be helpful to many students, engineers and researchers working in the field of carbon nanotubes.

Meta-Nanotubes are a new generation of carbon nanotubes (CNTs) which result from the chemical transformation of regular CNTs and their subsequent combination with foreign materials (atoms, molecules, chemical groups, nanocrystals) by various ways such as functionalisation, doping, filling, and substitution. These new nanomaterials exhibit enhanced or new properties, such as reactivity, solubility, and magnetism, which pristine CNTs do not possess. Their many applications include electronic and optoelectronic devices, chemical and biosensors, solar cells, drug delivery, and reinforced glasses and ceramics. Carbon Meta-Nanotubes: Synthesis, Properties and Applications discusses these third generation carbon nanotubes and the unique characteristics they possess. Beginning with a general overview of the subject, this book covers the five main categories of meta-nanotubes, namely: Doped Carbon Nanotubes Functionalised Carbon Nanotubes Decorated or Coated Carbon Nanotubes Filled Carbon Nanotubes Heterogeneous Nanotubes Providing unparalleled coverage of these third generation or meta-nanotubes, and possibilities for future development, this book is essential for anyone working on carbon nanotubes.

A crucial overview of the cutting-edge in nanocarbon research and applications In Synthesis and Applications of Nanocarbons, the distinguished authors have set out to discuss fundamental topics, synthetic approaches, materials challenges, and various applications of this rapidly developing technology. Nanocarbons have recently emerged as a promising material for chemical, energy, environmental, and medical applications because of their unique chemical properties and their rich surface chemistries. This book is the latest entry in the Wiley book series Nanocarbon Chemistry and Interfaces and seeks to comprehensively address many of the newly surfacing areas of controversy and development in the field. This book introduces foundational concepts in nanocarbon technology, hybrids, and applications, while also covering the most recent and cutting-edge developments in this area of study. Synthesis and Applications of Nanocarbons addresses new discoveries in the field, including: · Nanodiamonds · Onion-like carbons · Carbon nanotubes · Fullerenes · Carbon dots · Carbon fibers · Graphene · Aerographite This book provides a transversal view of the various nanocarbon materials and hybrids and helps to share knowledge between the communities of each material and hybrid type.

This book describes a series of contemporary techniques and their combinations used for CNTs solubilization, from physical to chemical and biological, applying inorganic and organic compounds, as well as some metal complexes. In some cases, successive steps can be applied, for instance the use of low and high-weight surfactants, or mineral acid treatment for creation of –OH and –COOH groups and their further interaction with organic molecules. Each discussed method leads to an improvement of CNT solubility, frequently a considerable one. The formed dispersions can be stable for long periods of time, from several weeks to some months, and they sometimes even remain stable after centrifugation. Several special studies have been carried out in the areas of influence of solvent and light on CNTs dispersibility, combinations and abilities of surfactants, CNT cytotoxicity, etc. Applications of solubilized CNTs are discussed in this book as well.

Chemically-modified carbon nanotubes (CNTs) exhibit a wide range of physical and chemical properties which makes them an attractive starting material for the preparation of super-strong and highly-conductive fibres and films. Much information is available across the primary literature, making it difficult to obtain an overall picture of the state-of-the-art. This volume brings together some of the leading researchers in the field from across the globe to present the potential these materials have, not only in developing and characterising novel materials but also the devices which can be fabricated from them. Topics featured in the book include Raman characterisation, industrial polymer materials, actuators and sensors and polymer reinforcement, with chapters prepared by highly-cited authors from across the globe. A valuable handbook for any academic or industrial laboratory, this book will appeal to newcomers to the field and established researchers alike.