The value of the critical temperature (Tc), below which the thermal explosion of a chemical cannot occur, is indispensable to prevent such a chemical from exploding. In order to determine the Tc it has so far been necessary to measure the value in explosion experiments. Because of the inherent hazards, only few Tc values are available at present. Critical Temperatures for the Thermal Explosion of Chemicals introduces new and simple procedures to calculate the Tc. As a result Tc can be calculated for a range of chemicals, many of which are listed in this new volume. The calculated values of Tc are shown to be in agreement with experimentally determined values. The data and methods presented in Critical Temperatures for the Thermal Explosion of Chemicals will be of use to research laboratories as well as in the chemical industry. - Introduces new and simple procedures for calculating critical temperatures - Lists the T(c) values of chemicals in tables - Explains mathematical expressions in clear simple terms

Completely revised and updated to reflect the current IUPAC standards, this second edition is enlarged by five new chapters dealing with the assessment of energy potential, physical unit operations, emergency pressure relief, the reliability of risk reducing measures, and process safety and process development. Clearly structured in four parts, the first provides a general introduction and presents the theoretical, methodological and experimental aspects of thermal risk assessment. Part II is devoted to desired reactions and techniques allowing reactions to be mastered on an industrial scale, while the third part deals with secondary reactions, their characterization, and techniques to avoid triggering them. Due to the inclusion of new content and restructuring measures, the technical aspects of risk reduction are highlighted in the new section that constitutes the final part. Each chapter begins with a case history illustrating the topic in question, presenting lessons learned from the incident. Numerous examples taken from industrial practice are analyzed, and each chapter concludes with a series of exercises or case studies, allowing readers to check their understanding of the subject matter. Finally, additional control questions have been added and solutions to the exercises and problems can now be found.

Proceedings of the NATO Advanced Study Institute on Chemistry and Physics of the Molecular Processes in Energetic Materials, Altavilla Milicia, Sicily, Italy, September 3-15, 1989

This book began as a program of self-education. While teaching under graduate physical chemistry, I became progressively more dissatisfied with my approach to chemical kinetics. The solution to my problem was to write a detailed set of lecture notes which covered more material, in greater depth, than could be presented in undergraduate physical chemistry. These notes are the foundation upon which this book is built. My background led me to view chemical kinetics as closely related to transport phenomena. While the relationship of these topics is well known, it is often ignored, except for brief discussions of irreversible thermody namics. In fact, the physics underlying such apparently dissimilar processes as reaction and energy transfer is not so very different. The intermolecular potential is to transport what the potential-energy surface is to reactivity. Instead of beginning the sections devoted to chemical kinetics with a discussion of various theories, I have chosen to treat phenomenology and mechanism first. In this way the essential unity of kinetic arguments, whether applied to gas-phase or solution-phase reaction, can be emphasized. Theories of rate constants and of chemical dynamics are treated last, so that their strengths and weaknesses may be more clearly highlighted. The book is designed for students in their senior year or first year of graduate school. A year of undergraduate physical chemistry is essential preparation. While further exposure to chemical thermodynamics, statistical thermodynamics, or molecular spectroscopy is an asset, it is not necessary.

This book is a basic reference providing concise, accurate definitions of the key terms and concepts of organic chemistry. Not simply a listing of organic compounds, structures, and nomenclatures, the book is organized into topical chapters in which related terms and concepts appear in close proximity to one another, giving context to the information and helping to make fine distinctions more understandable. Areas covered include: bonding, symmetry, stereochemistry, types of organic compounds, reactions, mechansims, spectroscopy, and photochemistry.

This book presents a systematic summary of a series of achievements of blast injury studies in China and the latest progress in blast injury treatment including injuries caused by various explosion accidents (such as coal mine gas explosion, and chemical explosion) and terrorist bombing around the world over the past three decades. The book not only covers comprehensive introductions to the knowledge and injury theories about explosive shock waves, but also expounds the prevention and treatment of various explosion shock injuries and their complications with generalized summaries. This book not only contains a diverse range of content, but also immense practicality. It elaborates on the causes of various types of explosion and impact injuries, as well as protection and treatment measures, serving not only as an important basis and technical support for military health service support in modern warfare, but is also extremely important in providing practical value in peacetime disaster prevention, mitigation and relief for patients.

Bretherick's Handbook of Reactive Chemical Hazards is an assembly of all reported risks such as explosion, fire, toxic or high-energy events that result from chemical reactions gone astray, with extensive referencing to the primary literature. It is designed to improve safety in laboratories that perform chemical synthesis and general research, as well as chemical manufacturing plants. Entries are ordered by empirical formula and indexed under both name(s) and Chemical Abstracts Registry Numbers. This two-volume compendium focuses on reactivity risks of chemicals, alone and in combination; toxicity hazards are only included for unexpected reactions giving volatile poisons - Predict, avoid, and control reactivity danger with this latest edition of the leading guide - Covers every chemical with documented information on reactive hazards; more than 5,000 entries on single elements or compounds, and 5,000 entries on the interactions between two or more compounds - Includes five years of new reports, new references to the primary literature, and amplification to existing entries - Links similar compounds or incidents that are not obviously related

The primary goal of the book is to promote research and developmental activities in energy, power technology and chemical technology. Besides, it aims to promote scientific information interchange between scholars from top universities, business associations, research centers and high-tech enterprises working all around the world. The conference conducted in-depth exchanges and discussions on relevant topics such as energy engineering and chemical engineering, aiming to provide an academic and technical communication platform for scholars and engineers engaged in scientific research and engineering practice in the field of energy materials, energy equipment and electrochemistry. By sharing the research status of scientific research achievements and cutting-edge technologies, it helps scholars and engineers all over the world comprehend the academic development trends and broaden research ideas. So as to strengthen international academic research, academic topics exchange and discussion, and promote the industrialization cooperation of academic achievements.

Significant loss to business occurs through fires in the workplace. Whether large or small, fire causes personal suffering, damage to plant, equipment and buildings, and loss of business. Fire legislation has changed over the past few years, especially with the introduction of European Directives. New regulations mean that employers have to carry out fire risk assessment and then, as a result of their findings, put in place control measures to prevent loss of life. Fire Hazards in Industry has been designed to cover, in general terms, exactly what is required of employers. It is written in simple language and considers the basics of good fire safety management. After reading Fire Hazards in Industry, any employer, safety professional or fire safety officer should be able to install a system for carrying out fire risk assessment. In addition to sections relating to the legal aspects of fire prevention, the book explains the concepts of fire modelling, explosions and combustion reactions. There is also a section relating to common industry fire hazards and hazards associated with electrical equipment. Knowledge of all these topics would be required if a person were to attempt to carry out fire risk assessment. Throughout the book, past case histories are used to illustrate certain aspects of fire and the causes of fire. The cases used have all been published by the Health and Safety Executive as a result of their investigations. These include; Abbeystead, Frodingham steelworks, HMS Glasgow, BP Grangemouth and many more.This book will be equally relevant to motor manufacturing as it is to the chemical industry. There are many case studies included that deal with fire hazards that are found in general industry.Fire Hazards in Industry is suitable for those who have relatively limited experience in fire safety and therefore use it as part of their career and educational development, but also can be used as reference material for those experienced professionals who have fire safety included in their day to day responsibility.