Providing a fundamental introduction to all aspects of modern plasma chemistry, this book describes mechanisms and kinetics of chemical processes in plasma, plasma statistics, thermodynamics, fluid mechanics and electrodynamics, as well as all major electric discharges applied in plasma chemistry. Fridman considers most of the major applications of plasma chemistry, from electronics to thermal coatings, from treatment of polymers to fuel conversion and hydrogen production and from plasma metallurgy to plasma medicine. It is helpful to engineers, scientists and students interested in plasma physics, plasma chemistry, plasma engineering and combustion, as well as chemical physics, lasers, energy systems and environmental control. The book contains an extensive database on plasma kinetics and thermodynamics and numerical formulas for practical calculations related to specific plasma-chemical processes and applications. Problems and concept questions are provided, helpful in courses related to plasma, lasers, combustion, chemical kinetics, statistics and thermodynamics, and high-temperature and high-energy fluid mechanics.

Plasma Chemistry is a collection of papers dealing with chemi-ionization kinetics, elementary chemical processes, kinetics in a non-equilibrium orquasi-equilibrium plasma, and heterogeneous reactions in plasmas of moderate pressure. Several papers discuss spectrometric plasma diagnostics, organic syntheses under plasma conditions, and the survival of plasma chemistry. One paper reviews chemi-ionization reactions, including reactions involving an electronically excited collision partner in which Penning ionization comparisons can be made. The paper also shows that observations made on noble gas metastables do not in apply to reactions of other species. Another paper analyzes the mechanism of plasma chemical reactions occurring under electron impact and through electronic-vibrational excited states. In these states, mutual influence of vibrational relaxation and dissociation becomes significant under low temperature plasma conditions. One paper discusses plasma techniques that have been applied to carry out various types of isomerizations or eliminations with high yields. The paper also shows the possibility of generating reactive species (atoms, radicals, carbenes) by these methods. The collection can prove useful for researchers, technicians, or scientists whose works involve organic chemistry, analytical chemistry, and other related fields of chemistry, such as physical chemistry and inorganic chemistry.

In addition to introducing the basics of plasma physics, Nonthermal Plasma Chemistry and Physics is a comprehensive presentation of recent developments in the rapidly growing field of nonthermal plasma chemistry. The book offers a detailed discussion of the fundamentals of plasma chemical reactions and modeling, nonthermal plasma sources, relevant

Low-temperature non-equilibrium gaseous discharges represent nearly ideal media for boosting plasma-based chemical reactions. In these discharges the energy of plasma electrons, after being received from the electromagnetic field, is transferred to the other degrees of freedom differently, ideally with only a small part going to the translational motion of heavy gas particles. This unique property enables the important application of non-equilibrium plasmas for greenhouse gas conversion. While the degree of discharge non-equilibrium often defines the energetic efficiency of conversion, other factors are also of a great importance, such as type of discharge, presence of plasma catalysis, etc. This book is focused on the recent achievements in optimization and understanding of non-equilibrium plasma for gas conversion via plasma modeling and experimental work.

Plasma Chemistry - 2: Plasma Chemistry and Transport Phenomena in Thermal Plasmas presents the proceeding of the Second International Symposium on Plasma Chemistry, held in Rome, Italy, on September 18–23, 1975. This book discusses the thermodynamic state of chemically reacting plasmas, which are generally described by Pauli or Boltzmann kinetic equations. Organized into eight chapters, this compilation of papers begins with an overview of the influence of the plasma state by a superimposed laser radiation field. This text then examines the mechanisms of chemical transformations in electric discharges. Other chapters consider the successful exploitation of thermal plasmas in the field of high temperature chemistry. This book discusses as well the status of plasma processes involving mass transfer and heat, with reference to the processes of condensation, vaporization, and chemical reaction. The final chapter deals with plasma heating and spraying of various materials. This book is a valuable resource for chemists, metallurgists, and scientists.

More than 99% of all visible matter in the universe occurs as highly ionized gas plasma with high energy content. Electrical low- and atmospheric-pressure plasmas are characterized by continuous source of moderate quantities of energy or enthalpy transferred predominantly as kinetic energy of electrons. Therefore, such energetically unbalanced plasmas have low gas temperature but produce sufficient energy for inelastic collisions with atoms and molecules in the gas phase, thus producing reactive species and photons, which are able to initiate all types of polymerizations or activate any surface of low reactive polymers. However, the broadly distributed energies in the plasma exceed partially the binding energies in polymers, thus initiating very often unselective reactions and polymer degradation. The intention of this book is to present new plasma processes and new plasma reactions of high selectivity and high yield. This book aims to bridge classical and plasma chemistry, particularly focusing on polymer chemistry in the bulk and on the surface under plasma exposure. The stability of surface functionalization and the qualitative and quantitative measurement of functional groups at polymer surface are featured prominently, and chemical pathways for suppressing the undesirable side effects of plasma exposure are proposed and illustrated with numerous examples. Special attention is paid to the smooth transition from inanimate polymer surfaces to modified bioactive polymer surfaces. A wide range of techniques, plasma types and applications are demonstrated.

Filling the gap for a book that covers not only plasma in gases but also in liquids, this is all set to become the standard reference for this topic. It provides a broad-based overview of plasma-chemical and plasmacatalytic processes generated by electrical discharges in gases, liquids and gas/liquid environments in both fundamental and applied aspects by focusing on their environmental and green applications and also taking into account their practical and economic viability. With the topics addressed by an international group of major experts, this is a must-have for scientists, engineers, students and postdoctoral researchers specializing in this field.

Fundamental Aspects of Plasma Chemical Physics - Thermodynamics develops basic and advanced concepts of plasma thermodynamics from both classical and statistical points of view. After a refreshment of classical thermodynamics applied to the dissociation and ionization regimes, the book invites the reader to discover the role of electronic excitation in affecting the properties of plasmas, a topic often overlooked by the thermal plasma community. Particular attention is devoted to the problem of the divergence of the partition function of atomic species and the state-to-state approach for calculating the partition function of diatomic and polyatomic molecules. The limit of ideal gas approximation is also discussed, by introducing Debye-Huckel and virial corrections. Throughout the book, worked examples are given in order to clarify concepts and mathematical approaches. This book is a first of a series of three books to be published by the authors on fundamental aspects of plasma chemical physics. The next books will discuss transport and kinetics.